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Monitoring the Formation of Coordination Complexes Using Electrospray Mass Spectrometry
Author(s): Mathieson JS (Mathieson, Jennifer S.)1, Cooper GJT (Cooper, Geoffrey J. T.)1, Pickering AL (Pickering, Alexandra L.)1, Keller M (Keller, Marco)1, Long DL (Long, De-Liang)1, Newton GN (Newton, Graham N.)1, Cronin L (Cronin, Leroy)1
Source: CHEMISTRY-AN ASIAN JOURNAL    Volume: 4    Issue: 5    Pages: 681-687    Published: 2009  
Times Cited: 1     References: 44     Citation MapCitation Map     
Abstract: cis,trans-1,3,5-Triaminocyclohexane (trans-tach) has been shown to be an excellent ligand in the synthesis of discrete complexes, molecular clusters, and infinite architectures. Herein, we report the Schiff-base derivitization of trans-tach to form cis,trans-1,3,5-tris (pyidine-2-carboxaldimino) cyclohexane (ttop), and the complexation of this ligand with copper(II) salts. The complexation reaction leads to the crystallization of transition-metal complexes with nuclearities of 1, 2, and 4, and the formation of the complexes can be followed stepwise, in real time, using electrospray mass spectrometry.
Document Type: Article
Language: English
Author Keywords: coordination modes; ligand design; mass spectrometry; Schiff bases; supramolecular chemistry
KeyWords Plus: ALIPHATIC AMINO LIGANDS; CRYSTAL-STRUCTURE; POLYMERS; CLUSTERS; CHAIN; ARCHITECTURES; CHEMISTRY; NETWORKS; COBALT; CAGES
Reprint Address: Cronin, L (reprint author), Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark Scotland
Addresses:
1. Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark Scotland
E-mail Addresses: L.Cronin@chem.gla.ac.uk
Publisher: WILEY-V C H VERLAG GMBH, PO BOX 10 11 61, D-69451 WEINHEIM, GERMANY
IDS Number: 450EB
ISSN: 1861-4728
DOI: 10.1002/asia.200900007
Cited by: 1
This article has been cited 1 times (from Web of Science).
Jiang W, Schafer A, Mohr PC, et al.  Monitoring Self-Sorting by Electrospray Ionization Mass Spectrometry: Formation Intermediates and Error-Correction during the Self-Assembly of Multiply Threaded Pseudorotaxanes  JOURNAL OF THE AMERICAN CHEMICAL SOCIETY  132  7  2309-2320  FEB 24 2010
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