The Cronin Group

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222
Integrated 3D-printed reactionware for chemical synthesis and analysis
M. D. Symes, P. J. Kitson, J. Yan, C. J. Richmond, G. J. T. Cooper, R. W. Bowman, T. Vilbrandt, L. Cronin
Nature Chem., 2012, 4, 349-354.

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221
Real-Time Ion-Flux Imaging in the Growth of Micrometer-Scale Structures and Membranes
B. Nemeth, M. D. Symes, A. G. Boulay, C. Busche, G. J. T. Cooper, D. R. S. Cumming, L. Cronin
Adv. Mat., 2012, 24, 1238-1242.

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220
Imaging the Belousov-Zhabotinsky reaction in real time using an ion sensitive array
L. Cronin, B. Nemeth, C. Busche, S. Tsuda, D. Cumming
Chem. Commun., 2012, 48, 5085-5087.

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219
Assembly of Molecular “Layered” Heteropolyoxometalate Architectures
J. Gao, J. Yan, S. Beeg, D.-L. Long, L. Cronin
Angew. Chem. Int. Ed., 2012, 51, 3373-3376.

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218
Nanoscale Growth of Molecular Oxides: Assembly of a {V6} Double Cubane Between Two Lacunary {P2W15} Polyoxometalates
C. Lydon, C. Busche, H. N. Miras, A. Delf, D.-L. Long, L. Yellowlees, L. Cronin
Angewandte Chemie International Edition, 2012, 51, 2115-2118.

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217
Solution-Phase Monitoring of the Structural Evolution of a Molybdenum Blue Nanoring
H. N. Miras, C. J. Richmond, D.-L. Long, L. Cronin
Journal of the American Chemical Society, 2012, Advanced article.

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216
Insights into the Self-Assembly Mechanism of the Modular Polyoxometalate “Keggin-Net” Family of Framework Materials and Their Electronic Properties
J. Thiel, P. I. Molina, M. D. Symes, L. Cronin
Cryst Growth Des, 2012, 12, 902-908.

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215
Spectroscopic studies of sulfite-based polyoxometalates at high temperature and high pressure
R. Q. Cabrera, S. Firth, C. S. Blackman, D.-L. Long, L. Cronin, P. F. McMillan
Journal of Solid State Chemistry, 2012, 186, 171-176.

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214
Switching between ring closed and open N-incorporated heterocycles with tuneable charges and modular reactivity based upon 5-(2-bromoethyl)phenanthridinium bromide
R. Eadie, C. Richmond, S. Moreton, L. Cronin
Organic & biomolecular chemistry, 2012, 10, 2026-2034.

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213
Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M(2)L(3) (M = Fe(2+), Cu(2+)) Complexes
F. Cui, S. Li, C. Jia, J. S. Mathieson, L. Cronin, X.-J. Yang, B. Wu
Inorg. Chem., 2012, 51, 179-187.

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212
Exploring the rotational isomerism in non-classical Wells–Dawson anions {W18X}: a combined theoretical and mass spectrometry study
L. Vilà-Nadal, S. G. Mitchell, D. L. Long, A. Rodríguez-Fortea, X. López, J. M. Poblet , L. Cronin
Dalton Trans., 2012, 41, 2264-2271.

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211
Exploring the mobility of nanoscale polyoxometalates using gel electrophoresis
R. Tsunashima, C. Richmond, L. Cronin
Chemical Science, 2012, 3, 343-348.

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210
An unprecedented silver-decavanadate dimer investigated using ion-mobility mass spectrometry
T. McGlone, J. Thiel, C. Streb, D.-L. Long, L. Cronin
Chem Comm, 2012, 48, 359-361.

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209
Observing the Hierarchical Self-Assembly and Architectural Bistability of Hybrid Molecular Metal Oxides Using Ion-Mobility Mass Spectrometry
J. Thiel, D. Yang, M. H. Rosnes, X. Liu, C. Yvon, S. E. Kelly, Y.-F. Song, D.-L. Long, L. Cronin
Angew Chem, 2011, 123, 9033-9037.

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208
Smart High-k Nanodielectrics Using Solid Supported Polyoxometalate-Rich Nanostructures
C. Musumeci, M. H. Rosnes, F. Giannazzo, M. D. Symes, L. Cronin, B. Pignataro
ACS Nano, 2011, 5, 9992-9999.

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207
Direct Synthesis and Mass Spectroscopic Observation of the {M40} Polyoxothiometalate Wheel
H. N. Miras, H. Zang, D.-L. Long, L. Cronin
Eur. J. Inorg. Chem., 2011, 33, 5105–5111.

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206
Connecting Theory with Experiment to Understand the Initial Nucleation Steps of Heteropolyoxometalate Clusters
L. Vila-Nadal, S. G. Mitchell, A. Rodriguez-Fortea, H. N. Miras, L. Cronin, J. M. Poblet
Phys. Chem. Chem. Phys., 2011, 13, 20136-20145.

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205
Modular Redox-Active Inorganic Chemical Cells: iCHELLs
G. J. T. Cooper, P. J. Kitson, R. S. Winter, M. Zagnoni, D.-L. Long, L. Cronin
Angew. Chem. Int. Ed., 2011, 50, 10373-10376.

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204
Investigating cation binding in the polyoxometalate-super-crown p(8) w(48) o(184) (40-)
T. Boyd, S. G. Mitchell, D. Gabb, D.-L. Long, L. Cronin
Chem. Eur. J., 2011, 17, 12010-12014.

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203
A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands
S. G. Mitchell, P. I. Molina, S. Khanra, H. N. Miras, A. Prescimone, G. J. T. Cooper, R. S. Winter, E. K. Brechin, D.-L. Long, R. J. Cogdell, L. Cronin
Angew. Chem. Int. Ed., 2011, 50, 9154-9157.

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202
Observation of Fe(v)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions
I. Prat, J. S. Mathieson, M. Güell, X. Ribas, J. M. Luis, L. Cronin, M. Costas
Nature Chem., 2011, 3, 788-793.

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201
Exploring the Structure and Properties of Transition Metal Templated {VM(17)(VO(4))(2)} Dawson-Like Capsules
H. N. Miras, D. Stone, D.-L. Long, E. J. L. McInnes, P. Koegerler, L. Cronin
Inorg. Chem., 2011, 50, 8384-8391.

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200
Combined Theoretical and Mass Spectrometry Study of the Formation-Fragmentation of Small Polyoxomolybdates
L. Vilà-Nadal, E. F. Wilson, H. N. Miras, A. Rodríguez-Fortea, L. Cronin, J. M. Poblet
Inorg. Chem., 2011, 50, 7811-7819.

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199
Amphiphilic Properties of Dumbbell-Shaped Inorganic-Organic-Inorganic Molecular Hybrid Materials in Solution and at an Interface
M. F. Misdrahi, M. Wang, C. P. Pradeep, F.-Y. Li, C. Lydon, L. Xu, L. Cronin, T. Liu
Langmuir, 2011, 27, 9193-9202.

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198
Process Understanding – Crystallization
L. Cronin, P. J. Kitson, C. C. Wilson
Process Understanding: For Scale-Up and Manufacture of Active Ingredients, 2011, 199-227.

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197
Electronic and photophysical properties of adducts of [Ru(bpy)3]2+ and Dawson-type sulfite polyoxomolybdates α/β-[Mo18O54(SO3)2]4−
J. J. Walsh, D.-L. Long, L. Cronin, A. M. Bond, R. J. Forster and T. E. Keyes
Dalton Trans., 2011, 40, 2038-2045 .

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196
Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32−: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}
M. N. Corella-Ochoa, H. N. Miras, A. Kidd, D.-L. Long and L. Cronin
Chem. Commun., 2011, 47, 8799-8801 .

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195
Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties
J. Gao, J. Yan, S. G. Mitchell, H. N. Miras, A. G. Boulay, D.-L. Long and L. Cronin
Chem. Sci., 2011, 2, 1502-1508 .

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194
Mapping the Sequential Self-Assembly of Heterometallic Clusters: From a Helix to a Grid
G. N. Newton, T. Onuki, T. Shiga, M. Noguchi, T. Matsumoto, J. S. Mathieson, M. Nihei, M. Nakano, L. Cronin, H. Oshio
Angew. Chemie Int. Ed., 2011, 50, 4844–4848.

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193
Hydrogen-Bonded Assemblies of Two-Electron Reduced Mixed-Valence [XMo12O40] (X = P and Si) with p-Phenylenediamines
T. Akutagawa, F. Kudo, R. Tsunashima, S. Noro, L. Cronin and T. Nakamura
Inorg. Chem., 2011, 50, 6711–6718.

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192
Design and Synthesis of “Dumb-bell” and “Triangular” Inorganic–Organic Hybrid Nanopolyoxometalate Clusters and Their Characterisation through ESI-MS Analyses
C. P. Pradeep, F.-Y. Li, C. Lydon, H. N. Miras, D.-L. Long, L. Xu, L. Cronin
Chem. Eur. J., 2011, 17, 7472-7479.

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191
Nanoscale polyoxometalate-based inorganic/organic hybrids
Y.-F. Song, D.-L. Long, C. Ritchie and L. Cronin
Chem. Rec., 2011, 11, 158–171.

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190
Silver Linked Polyoxometalate Open Frameworks (Ag-POMOFs) for the Directed Fabrication of Silver Nanomaterials
T. McGlone, C. Streb, M. Busquets-Fité, J. Yan, D. Gabb, D.-L. Long and L. Cronin
Cryst. Growth Des., 2011, 11, 2471–2478.

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189
The Crystal Computer: Computing with Inorganic Cellular Frameworks and Nets
M. D. Symes and L. Cronin
International Journal of Nanotechnology and Molecular Computation, 2011, 3, 24-34.

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188
Defining New Architectural Design Principles with 'Living' Inorganic Materials.
L. Cronin
Archit. Design, 2011, 34-43.

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187
Real-Time Observation of the Self-Assembly of Hybrid Polyoxometalates Using Mass Spectrometry
E. F. Wilson, H. N. Miras, M. H. Rosnes, L. Cronin
Angew. Chemie Int. Ed., 2011, 50, 3720-3724.

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186
Osmotically Driven Crystal Morphogenesis: A General Approach to the Fabrication of Micrometer-Scale Tubular Architectures Based on Polyoxometalates
G. J. T. Cooper, A. G. Boulay, P. J. Kitson, C. Ritchie, C. J. Richmond, J. Thiel, D. Gabb, R. Eadie, D.-L. Long, L. Cronin*
J. Am. Chem. Soc., 2011, 133, 5947–5954.

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185
A Supramolecular Heteropolyoxopalladate {Pd15} Cluster Host Encapsulating a {Pd2} Dinuclear Guest: [PdII2{H7PdII15O10(PO4)10}]9−
F. Xu, R. A. Scullion, J. Yan, H. N. Miras, C. Busche, A. Scandurra, B. Pignataro, D.-L. Long, L. Cronin
J. Am. Chem. Soc., 2011, 133, 4684–4686.

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184
Programmable Surface Architectures Derived from Hybrid Polyoxometalate-Based Clusters
C. Musumeci, A. Luzio, C.P. Pradeep, H.N. Miras, M. H. Rosnes, Y.F. Song, D.-L. Long, L. Cronin, B. Pignataro
J. Phys. Chem. C, 2011, 115, 4446-4455.

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183
Controlling the Molecular Assembly of Polyoxometalates from the Nano to the Micron Scale: Molecules to Materials
M. Hutin, D.-L. Long, L. Cronin
Israel Journal of Chemistry, 2011, 51, 205-214 .

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182
Extended Polyoxometalate Framework Solids: Two Mn(II)-Linked {P8W48} Network Arrays
S. G. Mitchell, T. Boyd, H. N. Miras, D.-L. Long, L. Cronin
Inorg. Chem., 2011, 50, 136–143 .

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181
Exploring the thermochromism of sulfite-embedded polyoxometalate capsules
R. Tsunashima, D.-L. Long, T. Endo, S. Noro, T. Akutagawa, T. Nakamura, R. Q. Cabrera, P. F. McMillan, P. Kögerler, L. Cronin
Physical Chemistry Chemical Physics, 2011, 13, 7295-7297 .

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180
Artificial photosynthesis – solar fuels: current status and future prospects
R. J. Cogdell, T. H. P. Brotosudarmo, A. T. Gardiner, P. M. Sanchez and L. Cronin
Biofuels, 2010, 1, 861-876 .

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179
Assembly of titanium embedded polyoxometalates with unprecedented structural features
T. McGlone, L. Vilà-Nadal, H. N. Miras, D.-L. Long, J. M. Poblet, L. Cronin
Dalton Trans., 2010, 39, 11599-11604.

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178
Assembly of Pure Silver-Tungsten-Oxide Frameworks from Nanostructured Solution Processable Clusters and Their Evolution into Materials with a Metallic Component
T. McGlone, C. Streb, D.-L. Long, L. Cronin
Advanced Materials, 2010, 22, 4275.

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177
Assembly of Modular Asymmetric Organic-Inorganic Polyoxometalate Hybrids into Anisotropic Nanostructures
M. H. Rosnes, C. Musumeci, C. P. Pradeep, J. S. Mathieson, D.-L. Long, Y.-F. Song, B. Pignataro, R. Cogdell and L. Cronin
J. Am. Chem. Soc., 2010, 132, 15490-15492 .

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176
A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core
S. G. Mitchell, H. N. Miras, D.-L. Long and L. Cronin
Inorganica Chimica Acta , 2010, 363, 4240-4246.

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175
Controlling transformations in the assembly of polyoxometalate clusters: {Mo11V7}, {Mo17V8} and {Mo72V30}
H.N. Miras, M.N.C. Ochoa, D.L. Long and L. Cronin
Chem. Commun., 2010, 46, 8148-8150.

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174
Reverse-Vesicle Formation of Organic-Inorganic Polyoxometalate-Containing Hybrid Surfactants with Tunable Sizes
J. Zhang,Y.-F. Song, L. Cronin and T. Liu
Chem. Eur. J., 2010, 16, 11320-11324.

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173
Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly
C. P. Pradeep, D.L. Long and L. Cronin
Dalton Transactions, 2010, 39, 9443-9457.

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172
Modular Inorganic Polyoxometalate Frameworks Showing Emergent Properties: Redox Alloys
J. Thiel, C. Ritchie, H. N. Miras, C. Streb, S. G. Mitchell, T. Boyd, M. N. C. Ochoa, M. H. Rosnes, J. McIver, D. L. Long and L.Cronin.
Angew. Chemie Int. Ed., 2010, 49, 6984-6988.

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171
In situ investigations of the polyoxometalate Trojan Horse compound K7Na[(W18O56)-O-VI(SO3)(2)(H2O)(2)]center dot 20H(2)O under high temperature and high pressure conditions
R. Q. Cabrera, D. L. Long, L. Cronin and P. F. McMillan
CrystEngComm, 2010, 12, 2568-2572.

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[published in Molecular Solids at Extreme Pressure themed issue]
170
Following the self assembly of supramolecular MOFs using X-ray crystallography and cryospray mass spectrometry
G. Seeber, G. J. T. Cooper, G. N. Newton, M. H. Rosnes, D. L. Long, B. M. Kariuki, P. Kögerler and L. Cronin
Chem. Sci, 2010, 1, 62-67.

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169
Self-Assembly of a Nanosized, Saddle-Shaped, Solution-Stable Polyoxometalate Anion Built from Pentagonal Building Blocks: [H34W119Se8Fe2O420](54-)
J. Yan, J. Gao, D. L. Long, H. N. Miras and L. Cronin
J. Am. Chem. Soc., 2010, 132, 11410-11411.

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168
Heat Capacity Reveals the Physics of a Frustrated Spin Tube
N. B. Ivanov, J. Schnack, R. Schnalle, J. Richter, P. Kögerler, G. N. Newton, L. Cronin, Y. Oshima, and H. Nojiri
Phys. Rev. Lett., 2010, 105, 037206.

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167
Development of a Building Block Strategy To Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO32- as a Template Linker
J. Yan, D.L. Long, L. Cronin
Angew. Chemie Int. Ed., 2010, 49, 4117-4120.

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166
Understanding and mapping the assembly of a family of trimeric polyoxometalates: transition metal mediated Wells-Dawson (M-18)-trimers
T. Boyd, S. G. Mitchell, H. N. Miras, D.L. Long and L. Cronin
Dalton Transactions, 2010, 39, 6460-6465.

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View 3D Structure : Ni-Dawson-Trimer
165
Supramolecular Architectures of Copper(II) Perchlorate Complexes of cis,trans-1,3,5-Triaminocyclohexane Assembled Exploiting the Delicate Balance Between Weak and Strong Interactions
M.N.C. Ochoa, G.J.T. Cooper, G.N. Newton, D.L. Long, G. Seeber & L. Cronin
Zeitschrift Fur Naturforschung Section B-A Journal Of Chemical Sciences, 2010, 65, 304-310.

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164
Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages
T. Shiga, G.N. Newton, J.S. Mathieson, T. Tetsuka, M. Nihei, L. Cronin & H. Oshio
Dalton Transactions, 2010, 39, 4730-4733.

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[Published in Molecular Magnets themed issue]
163
Cation Controlled Assembly and Transformation of Mono- and Bi-Sulfite Templated Dawson-Type Polyoxotungstates
J. Yan, D.L. Long, H.N. Miras & L. Cronin
Inorganic Chemistry, 2010, 49, 1819-1825.

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162
The Construction of High-Nuclearity Isopolyoxoniobates with Pentagonal Building Blocks: [HNb27O76](16-) and [H10Nb31O93(CO3)](23-)
R. Tsunashima, D.L. Long, H.N. Miras, D. Gabb, C.P. Pradeep & L.Cronin
Angew. Chemie Int. Ed., 2010, 49, 113-116.

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161
Controlled polymer synthesis-from biomimicry towards synthetic biology
G. Pasparakis, N. Krasnogor, L. Cronin, B.G. Davis & C. Alexander
Chemical Society Reviews, 2010, 39, 286-300.

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160
Hybrid polyoxometalate clusters with appended aromatic platforms
Y.-F. Song, D.L. Long & L. Cronin
CrystEngComm, 2010, 12, 109-115.

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159
Polyoxometalates: Building Blocks for Functional Nanoscale Systems
De-Liang Long, Ryo Tsunashima & Leroy Cronin
Angew. Chemie Int. Ed., 2010, 49, 1736-1758.

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[Review Article]
158
Face-directed self-assembly of an electronically active Archimedean polyoxometalate architecture
Scott G. Mitchell, Carsten Streb, Haralampos N. Miras, Thomas Boyd, De-Liang Long & Leroy Cronin
Nature Chemistry, 2010, 2, 308-312.

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View 3D Structure : W48-Cube
157
Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel
Haralampos N. Miras, Geoffrey J. T. Cooper, De-Liang Long, Hartmut Bögge, Achim Müller, Carsten Streb, Leroy Cronin
Science, 2010, 327, 72-74.

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View 3D Structure : Mo186
[Featured on the Front Cover]
156
Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster
S. Noro, R. Tsunashima, Y. Kamiya, K. Uemura, H. Kita, L. Cronin, T. Akutagawa, T. Nakamura
Ange. Chem. Int. Ed., 2009, 48, 8703-8706.

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155
Fine Tuning Reactivity: Synthesis and Isolation of 1,2,3,12b-Tetrahydroimidazo[1,2-f]phenanthridines
C. J. Richmond, R. M. Eadie, A. D. C. Parenty, L. Cronin
J. Org. Chem., 2009, 74, 8196-8202.

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154
Guest-Directed Supramolecular Architectures of {W-36} Polyoxometalate Crowns
T. McGlone, C. Streb, D.L. Long, L. Cronin
Chem. Asia. J., 2009, 4, 1612-1618.

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View 3D Structure no. 2 : W36crown-2
153
How to sweet-talk bacteria
G.J.T. Cooper and L. Cronin
Nature Chem., 2009, 1, 342-343.

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152
Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo-176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)(80)]Cl-27 center dot 450H(2)O
H. Imai, T. Akutagawa, F. Kudo, M. Ito, K. Toyoda, S. Noro, L. Cronin, T. Nakamura
J. Am. Chem. Soc., 2009, 131, 13578-13579.

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151
Supramolecular Silver Polyoxometalate Architectures Direct the Growth of Composite Semiconducting Nanostructures
C. Streb, R. Tsunashima, D. A. MacLaren, T. McGlone, T. Akutagawa, T. Nakamura, A. Scandurra, B. Pignataro, N. Gadegaard, and L. Cronin
Angew. Chem. Int. Ed., 2009, 48, 6490-6493.

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View 3D Structure : Silver-polyoxovanadate
150
Synthesis of Modular “Inorganic-Organic-Inorganic” Polyoxometalates and their Assembly into Vesicles
Chullikkattil P. Pradeep, Mauricio F. Misdrahi, Feng-Yan Li, Jie Zhang, Lin Xu, De-Liang Long, Tianbo Liu, Leroy Cronin
Angew. Chem. Int. Ed., 2009, 48, 8309-8313.

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149
The marriage of inorganic and organic building blocks for the assembly of rotaxanes
E. K. Brechin and L. Cronin
Angew. Chem. Int. Ed., 2009, 48, 8309-8313.

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148
A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion anion [(P4W6O34)2Co2Na2(H2O)2]18-
C. Ritchie, F. Li, C. P. Pradeep, D.-L. Long, L. Xu and L. Cronin
Dalton, 2009, 6483-6486.

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147
Synthesis of Cu(I) Octamolybdates using tetrakis-Acetonitrilecopper(I) Hexafluorophosphates
J. Fielden, D.-L. Long, L. Cronin, P. Kögerler
Polyhedron, 2009, 28, 2803-2807.

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146
A new C-C bond forming annulation reaction leading to pH switchable heterocycles
P. J. Kitson, A. D. C. Parenty, C. J. Richmond, D.-L. Long, and L. Cronin
Chem. Commun., 2009, 4067-4069.

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View 3D Structure no. 2 : compound-3
145
Real-Time Direction Control of Self Fabricating Polyoxometalate-Based Microtubes
G. J. T. Cooper, and L. Cronin
J. Am. Chem. Soc, 2009, 131, 8368–8369.

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144
Nucleation Mechanisms of Molecular Oxides: A Study of the Assembly-Disassembly of [W6O19]2– Using Theory and Mass Spectrometry
L. Vilà-Nadal, A. Rodríguez-Fortea, L.-K. Yan, E. F. Wilson, L. Cronin and J. M. Poblet
Angew. Chem. Int. Ed., 2009, 48, In Press.

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143
Voltammetry of [R4N]4[M18O54(SO3)2] and [Ru(bpy)3]2[M18O54(SO3)2] (M = Mo, W) as microcrystals adhered to a glassy carbon electrode surface in contact with ionic liquid media
M. Góral, T. McCormac, E. Dempsey, D.-L. Long, L. Cronin, A. M. Bond
Dalton Trans., 2009, 6727-6735.

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142
Discovery of Heteroatom ‘Embedded’ Te {W18O54} Nano- functional Polyoxometalates Using Cryospray Mass Spectrometry
J. Yan, D.-L. Long, E. F. Wilson, L. Cronin
Angew. Chem. Int. Ed., 2009, 48, 4376-4380.

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141
The Trinity of Polyoxometalates: Connecting {M12} Keggin and {M18} Dawson clusters to Triangles
S.G. Mitchell, S.Khanra, H. N. Miras, T. Boyd, D.-L. Long and L. Cronin
Chem. Commun., 2009, 2712–2714.

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View 3D Structure no. 2 : Trimeric-Keggin
140
Spontaneous Assembly and Real-Time Growth of Micron-Scale Tubular Structures from Polyoxometalate-Based Inorganic Solids
C. Ritchie, G. J. T. Cooper, Y.-F. Song, C. Streb, H. Yin, A. D. C. Parenty, D. A. MacLaren, and L. Cronin
Nature Chemistry, 2009, 1, 47-52.

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Highlighted on the front cover of issue 1, volume 1, 2009.
139
Heteroatom Controlled Kinetics of Switchable Polyoxometalate Frameworks
J. Thiel, C. Ritchie, C. Streb, D.-L. Long and L. Cronin
J. Am. Chem. Soc., 2009, 131, 4180-4181.

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138
Monitoring the Formation of Coordination Complexes Using Electrospray Mass Spectrometry
J. S. Mathieson, G. J. T. Cooper, A. L. Pickering, M. Keller, D.-L. Long, G. N. Newton, L. Cronin
Chem. Asia. J., 2009, 4, 681-687.

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View 3D Structure no. 5 : Compound-5
137
Micropatterned Surfaces with Covalently Grafted Unsymmetrical Polyoxometalate-hybrid Clusters Leads to Selective Cell Adhesion
Y.-F. Song, N. McMillan, D.-L. Long, S. Kane, J. Malm, M. O Riehle, C. P. Pradeep, N. Gadegaard, and L. Cronin
J. Am. Chem. Soc., 2009, 131, 1340-1341.

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136
Unravelling the Complexities of Inorganic and Supramolecular Self-Assembly in Solution with Electrospray and Cryospray Mass Spectrometry
H. N. Miras, E. F. Wilson and L. Cronin
Chem. Commun., 2009, 1297-1311.

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135
cis-Tach based Pentadecadentate Ligands as Building Blocks in the Synthesis of FeIII and PdII’ Coordination Clusters
G. N. Newton, G. J. T. Cooper, D. Schuch, T. Shiga, S. Khanra, D.-L. Long, H. Oshio and L. Cronin
Dalton Trans., 2009, 1549-1553.

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134
Grafting Ligands to Direct the Self-Assembly of Co/Ni2+ Substituted Polyoxometalate Clusters
C. Ritchie, T. Boyd, D.-L. Long and L. Cronin
Dalton Trans., 2009, 1587-1592.

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133
Exploring a Series of Isostructural Dodecanuclear Mixed Ni:Co Clusters: Controlling Elemental Composition using pH and Stoichiometry
G. J. T. Cooper, G. N. Newton, D.-L. Long, P. Kögerler, M. H. Rosnes, M. Keller, L. Cronin
Inorg. Chem., 2009, 48, 1097-1104.

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View 3D Structure no. 2 : Pd3-HACT
 
132
Controlling Nucleation of the Cyclic Heteropolyanion {P8W48} Two Cobalt-Substituted Phosphotungstate Networks
S. G. Mitchell, D. Gabb, C. Ritchie, D.-L. Long, L. Cronin
CrystEngComm, 2009, 11, 36-39.

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View 3D Structure : W48
131
Bottom-up’ Meets ‘Top-down’ Assembly in Nanoscale Polyoxometalate Clusters: Self Assembly of [P4W52O178]24- and Disassembly to [P3W39O134]19-
C. P. Pradeep, D.-L. Long, C. Streb and L Cronin
J. Am. Chem. Soc., 2008, 130, 14946-14947.

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130
Sorting the Assemblies of Unsymmetrically Covalently Functionalised Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry
Y.-F. Song, D.-L. Long, S. E. Kelly, L. Cronin
Inorg. Chem., 2008, 47, 9137-9139.

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129
Self-Assembly of Organic-Inorganic Hybrid Amphiphilic Surfactants with Large Polyoxometalates as Polar Head Groups
J. Zhang, Y.-F. Song, L. Cronin, T. Liu
J. Am. Chem. Soc., 2008, 130, 14408-14409.

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128
Hybrid host guest complexes: Directing the supramolecular structure through secondary host-guest interactions
C. Streb, T. McGlone, O. Brücher, D.-L. Long, L. Cronin
Chem. Eur. J, 2008, 14, 8861-8868.

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View 3D Structure : W36-complex
127
Solution Discovery and Solid State Characterisation of a Heterometallic Polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O529-SO3)]7-
H. N. Miras, D. J. Stone, Eric J. L. McInnes, R. Raptis, P. Baran, G. I. Chilas, M. P. Sigalas, T. A. Kabanos, L. Cronin
Chem. Commun., 2008, 4703-4705.

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View 3D Structure : Mo11V7
Featured on Cover
 
126
Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid
C. Ritchie, C. Streb, J. Thiel, S. G. Mitchell, H. N. Miras, D.-. Long T. Boyd, Robert D. Peacock, Thomas McGlone and L. Cronin
Angew. Chem., 2008, 47, 6881-6884.

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125
Realisation of a "lockable" molecular switch via pH & redox modulated cyclisation
C. J. Richmond, A. D. C. Parenty, Y.-F. Song, G. Cooke, and L. Cronin
J. Am. Chem. Soc., 2008, 130, 13059-13065.

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124
Polyoxometalate Mediated Self Assembly of Single-Molecule Magnets: {[XW9O34]2[MnIII4MnII2O4(H2O)4]}12-
C. Ritchie, A. Ferguson, H. Nojiri, H. N. Miras, Y.-F. Song, D.-L. Long, E. Burkholder, M. Murrie, P. Kögerler, E. K. Brechin, and L. Cronin
Angew. Chem. Int. Ed., 2008, 47, 5609-5612.

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123
Supramolecular self-assembly and anion-dependence of copper(II) complexes with cationic Dihydro-Imidazo Phenanthridinium (DIP)- containing ligands
Y.-F. Song, P. J. Kitson, D.-L. Long, A. D. C. Parenty, R. J. Thatcher, L. Cronin
CrystEngComm, 2008, 10, 1243-1251.

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View 3D Structure : Ligand
122
Structural Evolution of ‘S’ Shaped [H4W22O74]12- and ‘§’ Shaped [H10W34O116]18- polyoxotungstate Clusters
H. N. Miras, J. Yan, D.-L. Long, L. Cronin
Angew. Chem., 2008, 47, 8420-8423 .

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121
Probing the self-assembly of inorganic cluster architectures in solution with cryospray mass spectrometry: Growth of poly oxomolybdate clusters and polymers mediated by silver(I) ions
E. F. Wilson, H. Abbas, B. J. Duncombe, C. Streb, D.-L. Long, and L. Cronin
J. Am. Chem. Soc., 2008, 130, 13876-13884.

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120
Reversible electron-transfer reactions within a nanoscale metal oxide cage mediated by metallic substrates
C. Fleming, D.-L. Long, N. McMillan, J. Johnson, N. Bovet, V. Dhanak, N. Gadegaard, P. Kögerler, L. Cronin, M. Kadodwala
Nature Nano., 2008, 3, 229-233.

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119
Post-Synthetic Covalent Modification of Metal-Organic Framework (MOF) Materials
Y.-F. Song, L. Cronin
Angew. Chem., 2008, 47, 4635-4637.

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118
Capture of periodate in a {W18O54} cluster cage yielding a catalytically active polyoxometalate [H3W18O56(IO6)]6- embedded with high valent iodine
D.-L. Long, Y.-F. Song, E. F. Wilson, P. Kögerler, S.-X. Guo, A. M. Bond, J. S. J. Hargreaves and L. Cronin
Angew. Chem. Int. Ed., 2008, 47, 4384-4387.

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View 3D Structure : betaW18IO6
117
Supramolecular Metal Oxides: Programmed Hierarchical Assembly of a Protein-Sized 21 kD {(TBA)19[H2NC(CH2O)3P2V3W15O59]4 }5– Polyoxometalate Assembly
C. P. Pradeep, D-L. Long, G. N. Newton, Y.-F. Song, and L. Cronin
Angew. Chem. Int. Ed., 2008, 47, 4388-4391.

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View 3D Structure : Polyoxometalate-nanoassembly
116
Chemistry and supramolecular chemistry of chromium horseshoes
M. Rancan, G. N. Newton, C. A. Muryn, R. G. Pritchard, G. A. Timco, L. Cronin and R. E. P. Winpenny
Chem. Commun., 2008, 1560-1562.

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115
A Solid State Supramolecular Rotator Assembled from a Cs-crown Ether Polyoxometalate Hybrid:(Cs+)3([18]crown6)3(H+)2[PMo12O40]
T. Akutagawa, D. Endo, F. Kudo, S. I. Noro, S. Takeda, L. Cronin and T. Nakamura
Cryst. Growth Des., 2008, 8, 812-816.

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114
Polyoxometalate Nanocapsules: From Structure to Function
H.N. Miras, and L. Cronin
Organic Nanocapsules, 2008, Ed. J. Atwood and J. Steed.
 
113
Design of Hydrophobic Polyoxometalate Hybrid Assemblies Beyond Surfactant Encapsulation
Y.-F. Song, N. McMillan, D.-L. Long, J. Thiel, Y. Ding, H. Chen, N. Gadegaard, L. Cronin
Chem. Eur. J., 2008, 14, 2349-2354.

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112
Formation of a Pentanuclear Complex with a Hybrid Triazine-Phenanthridinone-based Ligand and the First Observation of a C-H•••p•••l.p. Interaction
P. J. Kitson, Y.-F. Song, P. Gamez, P. de Hoog, D.-L. Long, A. D. C. Parenty and L. Cronin
Inorg. Chem., 2008, 47, 1883-1885.

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View 3D Structure : Pd5
111
Polyoxometalate nanosystems
L. Cronin
Tomorrow's Chemistry Today, 2008, Ed. B. Pignataro.
110
Unravelling the Complexities of Polyoxometalates in Solution Using Mass Spectrometry: Protonation versus Heteroatom Inclusion
D. L. Long, C. Streb, Y. F. Song, S. Mitchell and L. Cronin
J. Am. Chem. Soc., 2008, 130, 1830-1832.

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109
One-pot synthesis of imidazopyridine derivatives
A. D. C. Parenty, L. Cronin
Synthesis, 2008, 9, 1479-1485.

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108
Trading Templates: Supramolecular Transformations between {CoII13} and {CoII12} Nanoclusters
G. N. Newton, G. J. T. Cooper, P. Kögerler, D. L. Long and L. Cronin
J. Am. Chem. Soc., 2008, 130, 790-791.

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View 3D Structure : Co13-trans-TACH
107
Isolation of extendable transition metals incorporated polyoxometalate intermediates with structural controls
G. Mitchell, C. Ritchie, D.-L. Long, L. Cronin
Dalton Trans., 2008, 1415-1417.

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View 3D Structure no. 3 : compound-3
106
Molecular Growth of Polyoxometalate Architectures Based on [-Ag{Mo8}Ag-] Synthons: Toward Designed Cluster Assemblies
H. Abbas, C. Streb, A. L. Pickering, A. R. Neil, D.-L. Long and L. Cronin
Cryst. Growth Des., 2008, 8, 635-642.

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[Highlighted on the front cover]
105
Nanoscale Assemblies of Gigantic Molecular {Mo154}-Rings: (Dimethyldioctadecyl ammonium)20 [Mo154O462H8(H2O)70]
T. Akutagawa, R. Jin, R. Tunashima, S. I. Noro, L. Cronin and T. Nakamura
Langmuir, 2008, 24, 231-238.

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104
Bridging the gap between solution and solid state studies in Poly-oxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties
H. N. Miras, D.-L. Long, P. Kögerler and L. Cronin
Dalton, 2008, 241-221.

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103
One-Pot Synthesis of Dihydroimidazo- and Imidazophenanthridinium Salts
A. D. C. Parenty and L. Cronin
Synthesis, 2008, 1, 155-160.
 
102
Directing Organic - Inorganic Hybrid Molecular-Assemblies of Polyoxometalate Crown-Ether Complexes with Supramolecular Cations
T. Akutagawa, D. Endo, S. I. Noro, and L. Cronin
Coord. Chem. Rev., 2007, 251, 2547-2561.

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101
Ligand and Counterion Control of Ag(I) Architectures: Assembly of a {Ag8} Ring Cluster Mediated by Hydrophobic and Ag...Ag Interactions
J. Fielden, D. L. Long, A. M. Z. Slawin, P. Koegerler, and L. Cronin
Inorg. Chem., 2007, 46, 9090-9097.

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100
pH-Dependence of the aqueous electrochemistry of the two-electron reduced - [Mo18O54(SO3)2] sulfite Dawson-like polyoxometalate anion derived from its triethanolammonium salt
B. Carole, S. W. Feldberg, A. M. Bond, D. L. Long, and L. Cronin
Dalton Trans., 2007, 4599-4607.

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99
Modular Assembly of a Functional Polyoxometalate-Based Open Framework Constructed from Unsupported AgI…AgI Interactions
C. Streb, C. Ritchie, D. L. Long, P. Koegerler, and L. Cronin
Angew. Chem. Int. Ed., 2007, 46, 7579-7582.

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View 3D Structure : Silver-Keggin-net
 
98
Controlled assembly and solution observation of a 2.6 nm polyoxometalate super tetrahedron cluster:[KFe12(OH)18(-1,2,3-P2W15O56)4]29–
C. P. Pradeep, D. L. Long, P. Kögerler, and L. Cronin
Chem. Commun., 2007, 4254-4256.

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97
From polyoxometalate building blocks to polymers and materials: The silver connection
Y.-F. Song, H. Abbas, C. Ritchie, N. McMillian, D.-L. Long, N. Gadegaard, and L. Cronin
J. Mater Chem., 2007, 17, 1903-1908.

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96
A General and Efficient Five-Step One-Pot Procedure Leading to Nitrogen-Bridgehead Heterocycles Containing an Imidazole Ring
A. D. C. Parenty, Y.-F. Song, C. J. Richmond, and L. Cronin
Org. Letts., 2007, 9, 2253-2256.

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95
Non covalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate- pyrene hybrid
Y.-F. Song, D.-L. Long, and L. Cronin
Angew. Chem. Int. Ed., 2007, 46, 3900-3904.

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94
Incorporation of N-heterocyclic cations into proteins with a highly directed chemical modification
N. McMillan, L. V. Smith, J. M. de la Fuente, A. D. C. Parenty, N. Gadegaard, A. R. Pitt, K. Thomson, C. MacKenzie, S. M. Kelly, and L. Cronin
Chem. Commun., 2007, 2581-2583.

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93
Supramolecular coordination chemistry
C. P. Pradeep and L. Cronin
Annu. Rep. Sec. A., 2007, 103, 287-332.

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92
Structural, Electrochemical, and Spectroscopic Characterization of a Redox Pair of Sulfite-Based Polyoxotungstates: a-[W18O54(SO3)2]4- and a-[W18O54(SO3)2]5-
N. Fay, A. M. Bond, C. Baffert, J. F. Boas, J. R. Pilbrow, D.-L. Long, L. Cronin
Inorg. Chem., 2007, 46, 3502-3510.

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91
Polyoxometalate Clusters, Nanostructures and Materials: From Self Assembly to Designer Materials and Devices
D. Long, E. Burkholder, and L. Cronin
Chem. Soc. Rev., 2007, 36, 105-121.

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90
Microcalorimetry of interaction of dihydro-imidazo-phenanthridinium (DIP)-based compounds with duplex DNA
K. M. Guthrie, A. D. C. Parenty, L. V. Smith, L. Cronin, A. Cooper
Biophys. Chem., 2007, 126, 117-123.

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89
Structural and Compositional Control in {M12} Cobalt and Nickel Coordination Clusters Observed Magnetochemically and with Cryospray Mass Spectrometry
Geoffrey J. T. Cooper, Graham N. Newton, Paul Kögerler, De-Liang Long, Larry Engelhardt, Marshall Luban and Leroy Cronin
Angew. Chemie, Int Ed., 2007, 46, 1340-1344.

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Highlighted on the cover.
 
88
Exploiting the Multifunctionality of Organocations in the Assembly of Hybrid Polyoxometalate Clusters and Networks
Chris Ritchie, Eric M Burkholder, De-Liang Long, David Adam, Paul Kögerler and Leroy Cronin
Chem. Commun., 2007, 468-470.

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Highlighted on the Cover
 
87
Engineering Porosity in a Chiral Heteropolyoxometalate-Based Framework: The Supramolecular Effect of Benzenetricarboxylic Acid
Carsten Streb, De-Liang Long and Leroy Cronin
Chem. Commun., 2007, 471-473.

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Highlighted on the Cover
 
86
Nanoscale Chemistry: A Route Towards Molecular Computers and Devices?
H. Abbas and L. Cronin
E. I. C., 2007, -.

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85
The imitation game—a computational chemical approach to recognizing life
Leroy Cronin, Natalio Krasnogor, Benjamin G Davis, Cameron Alexander, Neil Robertson, Joachim H G Steinke, Sven L M Schroeder, Andrei N Khlobystov, Geoff Cooper, Paul M Gardner, Peter Siepmann, Benjamin J Whitaker & Dan Marshn
Nature Biotech., 2006, 24, 1203-1206.

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84
Formation of p-Phenylenediamine-Crown Ether-[PMo12O40]4- Salts
Tomoyuki Akutagawa, Daigoro Endo, Hiroyuki Imai, Shin-ichiro Noro, Leroy Cronin, and Takayoshi Nakamura
Inorg. Chem., 2006, 45, 8628-8637.

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83
Anion Control of Isomerism, Crystal Packing and Binding Properties in a Mononuclear Zinc Complex
J. Fielden, P. T. Gunning, D. Long, M. Nutley, A. Ellern, P. Kögerler and L. Cronin
Polyhedron, 2006, 25, 3474-3480.

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82
Dihydro-Imidazo Phenanthridinium (DIP)-based DNA Binding Agents with Tuneable Structures and Biological Activity
L. V. Smith, A. D.C. Parenty, K. M. Guthrie, J. Plumb, R. Brown and L. Cronin
ChemBioChem, 2006, 7, 1757-1763.

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81
Influence of organic amines on the self-assembly of hybrid polyoxomolybdenum(V) phosphate frameworks
C. Streb, D.-L. Long, and L. Cronin
CrystEngComm, 2006, 8, 629-334.

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80
Linking up Chiral Clusters Using Molybdate Building Blocks: From Homochiral Supramolecular Arrays to Coordination Helices
D.-L. Long, P. Kögerler, L. J. Farrugia, and L. Cronin
Chem. Asian J., 2006, 1, 352-357.

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View 3D Structure : Fe3chain
 
79
Metal Dependant Formation of Mononuclear Complexes and M2L2 Mesocates with Schiff Based Ligands
J. F. Fielden, D. -L. Long, C. Evans, and L. Cronin
Eur. J. Inorg. Chem., 2006, 3930-3935.

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78
Supramolecular Coordination Chemistry
L. Cronin
Annu. Rep. Chem. Sect. A, 2006, 102, 353-378.

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77
Discovery of a fundamentally new family of isopolyoxo-tungstates, [H4W19O62]6-, encapsulating a {WO6} moiety within a {W18} Dawson-like cluster cage
D.-L. Long, P. Kögerler, A. D. C. Parenty, J. Fielden, and L. Cronin
Angew. Chemie. Int. Ed., 2006, 45, 4798-4803.

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View 3D Structure no. 2 : gama-W19
 
76
Experimental and Theoretical Investigations of the Sulfite-based Polyoxometalate Cluster Redox Series: α- and β-[Mo18O54(SO3)2]4-/5-/6-
C. Baffert, J. F. Boas, A. M. Bond, P. Kögerler, D.-L. Long, J. R. Pilbrow, and L. Cronin
Chem. Eur. J., 2006, 12, 8472-8483.

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75
Inorganic Crown Ethers: The Host-Guest Chemistry of A High Nuclearity ‘Celtic-Ring’ Isopolyoxotungstate [H12W36O120]12–
D. -L. Long, O. Brucher, C. Streb and L. Cronin
Dalton Trans., 2006, 2852-2860.

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Highlighted on the Cover
 
74
Synthetic, Structural & Magnetic Characterisation of a One-Dimensional Nickel Chain Constructed Using cis,trans-1,3,5-Triaminocyclohexane as a Building Block
G. N. Newton, G. J. T. Cooper, D. -L. Long, P. Kögerler and L. Cronin
J. Mol. Struc., 2006, 796, 23-27.

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73
Observation and Theoretical Analysis of the “Sensitive Coordination Sites” in the Isopoly-oxomolybdate Cluster [Mo36O112(H2O)14]8-
D. -L. Long, C. Streb, P. Kögerler and L. Cronin
J. Clus. Sci., 2006, 17, 257-266.

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View 3D Structure : mo36
 
72
Towards Polyoxometalate Integrated Nanosystems
D.-L. Long and L. Cronin
Chem. Eur. J., 2006, 12, 3698-3706.

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71
One-Pot Synthesis of Imidazophenanthridinium Salts
Y.-F. Song, L. V. Smith, E. Burkholder, and L. Cronin
Synfacts, 2006, 6, 554.
 
70
Unsymmetrical surface modification of a heteropolyoxo-tungstate via in-situ generation of monomeric and dimeric copper(ii) species
C. Ritchie, E. Burkholder, P. Kögerler and L. Cronin
Dalton Trans., 2006, 1712-1714.

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69
Inducing Molecular Growth in an {Mo57Fe6}-type Nanocluster: Synthesis, Structure, and Properties of {Mo57(Mo2)FeIII6}
J. Fielden , Y. L. Malaestean, A. Ellern, R. Garcia-Serres, L. Cronin and P. Kögerler
J. Clus. Sci., 2006, 17, 291-302.

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68
Inorganic Molecular Capsules: From Structure to Function
L. Cronin
Angew. Chemie Int. Ed., 2006, 45, 3576-3578.

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67
Discovery of an imidazo-phenanthridine synthon produced in a five-step one-pot reaction' leading to a new family of heterocycles with novel physical properties
A. D. C. Parenty, K. M. Gutrie, Y.-F. Song, L. V. Smith, E. Burkholder and L. Cronin
Chem. Commun., 2006, 1194-1196.

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Highlighted on the inside-front cover
 
66
Controlling Aggregation of Copper(II)-Based Coordination Compounds: From Mononuclear to Dinuclear, Tetranuclear, and Polymeric Copper Complexes
J. Fielden, J. Sprott, D.-L. Long, P. Kögerler and L. Cronin
Inorg. Chem., 2006, 45, 2886-2895.

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65
Preparation imidazophenanthridiniums and related compounds as anticancer agents
A. D. C. Parenty, R. Brown, L. Cronin
Patent WO, 2005, 122pp.

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64
Photonic crystal and photonic wire device structures
R. De La Rue, M. Sorel, N. Johnson, F. Rahman, C. Ironside, L. Cronin, I. Watson, R. Martin, C. Jin, P. Pottier, H. Chong, M. Gnan, A. Jugessur, E. Camargo, G. Erwin, A. Md Zain, I. Ntakis, L. Hobbs, H. Zhang, M. Armenise, C. Ciminelli, D. Coquillat
Proc SPIE - The International Society for Optical Engineering, 2005, 595004/1-595004/12.

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63
The importance of p-p, p-CH and N-CH interactions in the crystal packing of Schiff-base derivatives of cis,cis- and cis,trans-1,3,5-triaminocyclohexane
A. L. Pickering, G. Seeber, D.-L. Long, L. Cronin
CrystEngComm, 2005, 7, 504-510.

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62
Does it bind? An instant binding assay for DNA oligonucleotide interactive small molecules
S. V. Smith, J. M. de la Fuente, K. M. Guthrie, A. D. C. Parenty, L. Cronin
New J. Chem., 2005, 29, 1118-1120.

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61
Coordination Clusters
J. Fielden and L. Cronin, Eds., J. L. Atwood, J. W. Steed
Encyclopaedia of Supramolecular Chemistry, 2005, DOI: 10.1081/E-ESMC-120024346.

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60
Quantum Dots Protected with Tiopronin: A New Fluorescence System for Cell-Biology Studies
J. M. de la Fuente, M. Fandel, C. C. Berry, M. Riehle, L. Cronin, G. Aitchison, A. S. G. Curtis
ChemBioChem, 2005, 6, 989-991.

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Highlighted on the Cover
 
59
Supramolecular Coordination Chemistry
L. Cronin
Annu. Rep. Chem., Sect. A, 2005, 101, 348-374.

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58
Design and Sterospecific Synthesis of Modular Ligands Based upon cis -1,3- trans -5-Substituted Cyclohexanes
J. Fielden, J. Sprott and L. Cronin
New J. Chem., 2005, 29, 1152-1158.

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57
An Unusual Substitution Reaction Directed by an Intramolecular Re-arrangement
A. D. C. Parenty, L. V. Smith and L. Cronin
Tetrahedron, 2005, 61, 8410-8418.

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56
Macrocyclic Coordination Chemistry
L. Cronin
Annu. Rep. Chem., Sect. A, 2005, 101, 319-347.

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55
A Novel Copper (II) Metallacycle as a Building Block for the Assembly of an Extended Supramolecular Array Containing Channels and Helical Chains
G. J. T. Cooper, D.-L. Long and L. Cronin
Inorg. Coord. Chem Commun., 2005, 8, 737-739.

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View 3D Structure : alphaW18SO3
 
54
Highly Stable Phenanthridinium Frameworks as a New Class of Tunable DNA Binding Agents with Cytotoxic Properties
A. D. C. Parenty, L. V. Smith, K. M. Guthrie, D.-L. Long, J. Plumb, R. Brown, and L. Cronin
J. Med. Chem., 2005, 48, 4504-4506.

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53
Synthesis, Structure and Magnetism of a linear Cu-Cl-Cu entity found in [(Cu(Htach)(tach))2(µ-Cl)]5+
G. Seeber, B. M. Kariuki, L. Cronin, Paul Kögerler
Polyhedron, 2005, 24, 1651-1655.

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52
Confined Electron Transfer Reactions within a Molecular Metal Oxide 'Trojan Horse'
D.-L. Long, H. Abbas, P. Kögerler and L. Cronin
Angew. Chemie In. Ed., 2005, 44, 3415-3419.

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View 3D Structure : trojanhorseW18SO3
Highlighted on the Cover
 
51
Polyoxometalate nanostructures, superclusters, and colloids: From functional clusters to chemical aesthetics
P. Kögerler P and L. Cronin
Angew. Chemie In. Ed., 2005, 44, 844-846.

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50
Reactions of a {Mo16}-type polyoxometalate cluster with electrophiles: a synthetic, theoretical and magnetic investigation
D. L. Long, P. Kogerler, L. J. Farrugia, and L. Cronin
Dalton Trans., 2005, 1372-1380.

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49
Controllable Growth of Chains and Grids from Polyoxomolybdate Building Blocks Linked by Silver(I) Dimers
H. Abbas, A. L. Pickering, D.-L. Long, P. Kögerler, and L. Cronin
Chem. Eur. J., 2005, 11, 1071-1078.

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Highlighed as a Frontispiece
 
48
A High Nuclearity 'Celtic-Ring' Isopolyoxotungstate: [H12W36O120]12–
D.-L. Long, Hamera Abbas, P. Kögerler, and L. Cronin
J. Am. Chem. Soc., 2004, 126, 13880-13881.

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View 3D Structure : H12W36O120
 
47
Synthesis, structure and complexation of a large 28-mer macrocycle containing two binding sites for either anions or metal ions
L. Cronin, P.A. McGregor, S. Parsons, S. Teat, R. O. Gould, V. A. White, N. J. Long, N. Robertson
Inorg. Chem., 2004, 43, 8023-8029.

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46
Pentadecadentate Chelating Ligands as Building Blocks for an {Fe6} Cage with 12 Exo-coordinated Sodium Cations
G. J. T. Cooper, H. Abbass, D.-L. Long, P. Kögerler, L. Cronin
Inorg. Chem., 2004, 43, 7266-7268.

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45
Magnetic characterization of a novel frustrated three-leg ladder compound
J. Schnack, H. Nojiri, P. Kögerler, G. J. T. Cooper, L. Cronin
Phys. Rev. B., 2004, 70, 174420-1-174420-5.

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44
Old Clusters with New Tricks: An Unprecedented Family of Dawson Clusters Encapsulating Two Sulfite Anions Engineering a Short S…S Interaction and the First Example of a Metal Cluster Showing Thermochromic-Type Behaviour
D.L. Long, P. Kögerler, L. Cronin
Angew. Chemie Int. Ed., 2004, 43, 1817-1820.

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View 3D Structure no. 2 : betaMo18SO3
 
43
General “One-Pot-Three-Step” Methodology Leading to an Extended Class of N-Heterocyclic Cations: Spontaneous Nucleophilic Addition, Cyclisation and Hydride Loss
A. D. C. Parenty, L. V. Smith, A. L. Pickering, D.-L. Long, L. Cronin
J. Org. Chem., 2004, 69, 5934-5946.

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42
Facile Synthesis and Structures of Infinite One-Dimensional Silver(I) Coordination Polymers
A. L. Pickering, G. J. T. Cooper, D.-L. Long, L. Cronin
Polyhedron, 2004, 23, 2075-2079.

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41
Coordination Networks Through the Dimensions: From Discrete Clusters to 1D, 2D and 3D Silver(I) Coordination Polymers with Rigid Aliphatic Amino Ligands
A. L. Pickering, D.-L. Long, L. Cronin
Inorg. Chem., 2004, 43, 4953-4961.

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40
Secondary coordination sphere controlled reversible geometry reorganisations in copper(II) complexes
J. Fielden, D.-L. Long, L. Cronin
Chem. Commun., 2004, 2156-2157.

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39
Supramolecular assembly of ligand-directed triangular {CuII3Cl} clusters with spin frustration and spin-chain behaviour
G. Seeber, P. Kögerler, B. M. Kariuki, L. Cronin
Chem. Commun., 2004, 1580-1581 .

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38
Polymeric Silver(I) Coordination Tubes
A. L. Pickering, G. Seeber, D. Long, L. Cronin
Chem. Commun., 2004, 136-137.

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37
DNA as a Supramolecular Scaffold
A. L. Pickering and L Cronin, Eds., J. L. Atwood, J. W. Steed
Encyclopaedia of Supramolecular Chemistry, 2004, p467-474.

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36
High Nuclearity Clusters: Iso and Heteropolyoxoanions and Relatives
L. Cronin, Eds., J. A McCleverty, T. J. Meyer
Comprehensive Coordination Chemistry II, 2004, 7, p1-57.

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35
Macrocyclic and Supramolecular Coordination Chemistry
L. Cronin
Annu. Rep. Chem., Sect. A, 2004, 100, 323-383.

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34
Palladium(II)-based cis,trans-1,3,5-triaminocyclohexane complexes demonstrating a variety of coordination modes and architectures
G. Seeber, D. L. Long, B. Kariuki, L. Cronin
Dalton Trans., 2003, 4498-4504.

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33
Macrocyclic and Supramolecular Coordination Chemistry
L. Cronin
Annu. Rep. Prog. Chem., Sect. A, 2003, 99, 289-347.

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32
The Missing Link in Low Nuclearity Pure Polyoxovanadate Clusters: Preliminary Synthesis and Structural Analysis of a New {V16} Cluster and Related Products
D.-L. Long, D. Orr, G. Seeber, P. Koegerler, L. J. Farrugia, and L. Cronin
J. Clus. Sci., 2003, 14, 313-324.

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View 3D Structure : H2V16O38
 
31
Synthesis and structure of [Zn(OMe)(L)]. [Zn(OH)(L)]2(BPh4), L = cis,cis-1,3,5-tris[(E,E)-3-(2-furyl) acrylideneamino] cyclohexane: structural models of carbonic anhydrase and liver alcohol dehydrogenase
L. Cronin, P. H. Walton
Chem Commun., 2003, 1572-1573.

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30
Restraining symmetry in the formation of small polyoxomolybdates: New building blocks of unprecedented topology resulting from ‘shrink-wrapping' [H2Mo16O52]10- type clusters
D. Long, P. Kögerler, L. J. Farrugia, L. Cronin
Angew. Chemie Int. Ed., 2003, 42, 4180-4183.

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View 3D Structure no. 2 : mo16

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29
Controlling Dimensionality of Silver(I) Coordination Networks with Rigid Aliphatic Amino Ligands: From a 2D to a 3D Network of Unprecedented Topology Comprising Helical Channels
G. Seeber, A. Pickering, D. Long, L. Cronin
Chem. Commun., 2003, 2002-2003.

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28
Polyoxomolybdate Clusters: Nanoscopic Wheels and Balls
L. Cronin , E. Diemann, A. Müller (Editor: J. D. Woollins)
Inorganic Experiments, Wiley-VCH, Weinheim, 2003, 340-346.
 
27
Self-assembly of a twelve-component hexanuclear metallomacrocycle constructed with a novel tri-amino ligand
G. Seeber, B. M. Kariuki, L. Cronin
Chem. Commun., 2002, 2912-2913.

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26
A novel polyoxometalate chain formed from heteropolyanion building blocks and rare earth metal ion linkers: [La(H2O)7Al(OH)6Mo6O18]
V. Shivaiah, P. V. Narasimha-Reddy, L. Cronin, S. K. Das
Dalton, 2002, 3781-3782.

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Highlighted on the Cover
 
25
"Molecular symmetry breakers" generating metal-oxide-based nanoobject fragments as synthons for complex structures: [{Mo128Eu4O388H10(H2O)81)}2]20-, a giant-cluster dimer
L. Cronin , C. Beugholt, E. Krickemeyer, M. Schmidtmann, H. Bögge, P. Koegerler, T. K. K. Luong, and A. Mueller
Angew. Chem. Int. Ed., 2002, 41, 2805-2808.

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24
Metal bis-1,2-dithiolene complexes in conducting and magnetic crystalline assemblies
N. Robertson and L. Cronin
Coord. Chem. Rev., 2002, 227, 93-127.

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23
Nanosized Inorganic Clusters and Cages
L. Cronin, D. Fenske, A. Müller
Encyclopedia of Physical Science and Technology Vol. 10, 3rd Edition, 2002, 303-317.
 
22
The Potential of Pentagonal Building Blocks: From Giant Ring-shaped to Spherical Polyoxometalate Clusters
L. Cronin (Ed. G. Meyer, D. Naumann, L Wesemann)
Inorganic Chemistry Highlights, Wiley-VCH, Weinheim, 2002, 113-121.

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21
Syntheses and Structures of M (L)(X)(BPh4) Complexes, M = Co(II), Zn(II); L = cis -1,3,5-tri[(2-furyl)-propenylideneamino] cyclohexane, X = OAc, NO3 and 2-hydroxybenzoate: Structural Models of the Active Site of Carbonic Anhydrase
L. Cronin, S. P. Foxon, P. J. Lusby and P. H. Walton
J. Bio. Inorg. Chem., 2001, 6, 367-377.

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20
Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: isolation of an intermediate in C-F bond activation
T. Braun, L. Cronin , C.L. Higgitt, J.E. McGrady, R.N. Perutz, and M. Reinhold
New J. Chem., 2001, 25, 19-21.

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19
Unique structural topologies involving metal-metal and metal-sulphur interactions: Salts of [Ni(dmit)2]x- with dicyclohexyl-18-crown-6 complexed counterions


L. Cronin , S. J. Clark, S. Parsons, T. Nakamura and N. Robertson
Dalton Trans., 2001, 1347-1351.

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18
Towards the construction of mesoscopic species with emergent and functional properties via the derivatisation of molybdenum-oxide 'Giant-Wheel' clusters
L. Cronin, C. Beugholt and A. Müller
J. Mol. Struc. Theochem., 2000, 500, 181-193.

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17
Controlling growth of novel solid-state materials via discrete molybdenum-oxide-based building blocks as synthons
L. Cronin , P. Kögerler and A. Müller
J. Solid State Chem., 2000, 152, 57-67.

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16
4-(4-chloro-3-nitro-benzoamide)-3-nitrobenzonitrile
L. Cronin , D. J Adams, D.J Nightingale and J. H .Clark
Acta Cryst. C, 2000, 56, 244-245.

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15
Structure and dynamic exchange in rhodium eta(2)-naphthalene and rhodium eta(2)-phenanthrene complexes: Quantitative NOESY and EXSY studies
L. Cronin , C. L. Higgitt, R. N. Perutz
Organometallics, 2000, 19, 672-683.

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14
A new class of macrocycle capable of binding exogenous metals: Synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1,4,8,11-tetraaza-cyclotetradecane-2,3-dione [exoO2cyclam]
L. Cronin , A. R. Mount, N. Robertson and S. Parsons
Dalton Trans., 1999, 1925-1927.

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13
Control of copper(II) coordination geometry via supramolecular assembly of ligands in the solid state
D. J. White, L. Cronin , S. Parsons, N. Robertson, P. A. Tasker and A. P. Bisson
Chem. Commun., 1999, 1107-1108.

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12
catena-poly[diamminecopper(II)-m-acetato-O:O'] tetrafluoroborate
L. Cronin , M. Harper, P. H. Walton and C. Lindsay
Acta Cryst. C, 1998, 54, 1255-1257.

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11
Self-assembly preparation, structure and magnetic studies of a novel dinuclear copper(II) complex: [Cu2(mOH)(mOAc)(m-L)][BF4]2 [L = bis-1,3-( cis,cis -1,3,5-triaminocyclohexane)xylyli-diene]
C. J. Boxwell, R. Bhalla, L. Cronin, S.S Turner and P. H. Walton
Dalton Trans., 1998, 2449-2450.

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10
Synthesis, structure and reactivity of N,O-metallacyclic (dicarbonyldiazene) platinum complexes
D. Chan, L. Cronin , S. B. Duckett, P. Hupfield and R. N. Perutz
New J. Chem., 1998, 511-516.

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9
Synthesis and single crystal X-ray structure of a novel trinuclear copper(II) methoxide complex
L. Cronin and P. H. Walton
Inorganica Chimica Acta, 1998, 269, 241-245.

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8
Rapid intermolecular carbon-fluorine bond activation of pentafluoropyridine at nickel(0): Comparative reactivity of fluorinated arene and fluorinated pyridine derivatives
L. Cronin, C. L. Higgit, R. Karch and R. N. Perutz
Organometallics, 1997, 16, 4920-4928.

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7
Functional and Structural Model Complexes of Zinc Metalloenzymes Using Ligands Based on cis,cis -1,3,5-Triaminocyclohexane
L. Cronin and P. H. Walton
J. Inorg. Biochem., 1997, 67, 221-221.

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6
A cyclic monomer of tetraethyleneglycol succinate
L. Cronin , M. H. Moore, J. A. Semylen and B. R. Wood
Acta Cryst. C, 1997, 53, 940-942.

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5
Methylhexamethylenetetramine fluoride tetrahydrate: MeHMTAF.4H2O
L. Cronin , D. J. Nightingale and J. H. Clark
Acta Cryst. C, 1997, 53, 789-791.

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4
Syntheses and single-crystal X-ray structures of a series of monosubstituted cis,cis -1,3,5-triaminocyclohexane-based complexes
L. Cronin , B. Greener, S. L. Heath, S. P. Foxon and P. H. Walton
Inorg. Chem., 1997, 36, 2594-2600.

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3
Preparations and Structures of 2 cis,cis-1,3,5-triaminocyclohexane-based Complexes Containing Hydrogen-Bonded Solvent Molecules
L. Cronin , B. Greener, M. H. Moore and P. H. Walton
Dalton Trans., 1996, 3337-3339.

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2
Preparation and Structures of a Series of Novel, Monosubstituted cis,cis -1,3,5-Triaminocyclohexane-based Complexes
B. Greener, L. Cronin , G. D. Wilson and P.H. Walton
Dalton Trans., 1996, 401-403.

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1
Laser Flash-Photolysis and Matrix-Isolation Studies of Ru[R2PCH2CH2 PR2]2H2 (R=C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents
L. Cronin , C. N. Nicasio, R. N. Perutz, R. G. Peters, D.M Roddick and M.K. Whittlesey
J. Am. Chem. Soc., 1995, 117, 10047-10054.

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