R. D. PEACOCK - RECENT PUBLICATIONS (1998 - 2008)

  1. Enantioselective regulation of a metal complex in reversible binding to serum albumin: dynamic helicity inversion signaled by circularly polarized luminescence, C.P. Montgomerie, E.J. New, D. Parker and R.D. Peacock, Chem. Comm. , 2008, 4261-4263.

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  2. Reversible redox reactions in an extended polyoxometalate framework solid, C. Ritchie, C. Streb, J. Thiel, S.G. Mitchell, H.N. Miras, D.L. Long, T. Boyd, R.D. Peacock, T. McGlone, and L. Cronin, Angew. Chem. Int. Ed., 2008, 47, 6881-6884.

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  3. Cobalt(II) citrate cubane single-molecule magnet, K.W. Galloway, A.M. Whyte, W. Wernsdorfer, J. Sanchez-Benitez, K.V. Kamenev, A. Parkin, R.D. Peacock and M. Murrie Inorg. Chem., 2008, 47, 7438-7442

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  4. Emeritus Professor Stephen Mason,R.D. Peacock and B. Stewart, RSC News, March 2008, p22. (fuller version at http://www.rsc.org/obituaries)

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  5. Orthoaxial Single Crystal X-ray Circular and Linear Dichroism of the 1s ® 3d transition of {2L-[Co(en)3]Cl3}2.NaCl.6H2O: measurement of the absolute values of the quadupole and dipole contributions to the intensity of a pre-edge transition, R. D. Peacock, T. Prosperi and B. Stewart, Chem. Phys. Letters, 2007, 444, 375-378.

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  6. Self-assembly of Chiral Luminescent Lanthanide Co-ordination Bundles, J.P. Leonard, P. Jensen, T. McCabe, J.E. O’Brian, R,D,Peacock, P.E. Kruger and T. Gunnlaugsson, J. Amer. Chem. Soc., 2007, 129, 10986-10987.

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  7. Experimental Charge Density Study on the Ni(II) Coordination Complex [Ni(H3L)][NO3][PF6] [H3L = N,N',N''-Tris(2-hydroxy-3-methylbutyl)-1,4,7-triazacyclononane : A Reappraisal,L. J. Farrugia, C. S. Frampton, J. A. K. Howard, P. R. Mallinson, R. D. Peacock, G. T. Smith, and B.Stewart, Acta Crystallogr. B, 2006, 62, 236-244.

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  8. Synthesis and Characterisation of Highly Emmissive and Kinetically Stable Lanthanide Complexes suitable for usage in cellulo, R.A. Poole, G. Bobba, M.J. Cann, J-C. Frias, D. Parker and R.D. Peacock, Org.and Biomolec. Chem., 3, 1013 - 1024 (2005).

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  9. Synthesis and Binding Properties of of Hybrid cyclophane-Azomacrocyclic Receptors, P. Gunning, A.C. Benniston and R.D. Peacock, J. Org. Chem. ,70, 115-123 (2005).

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  10. A Modular Ditopic Crown-Shielded Phosphate Ion Pair Receptor, P. Gunning. A.C. Benniston and R.D. Peacock, Chem. Commun. 2226-2227 (2004).

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  11. Core electron Transitions as a probe for molecular chirality – Natural Circular Dichroism at the carbon K-edge of methyloxirane, S. Turchini, N. Zema, L. Alagna, B. Stewart, R.D. Peacock and T. Prosperi, J. Amer. Chem. Soc., 2004, 126, 4532 - 4533.

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  12. "Chiral Molecules Spectroscopy", R D Peacock and B Stewart, in Comprehensive Coordination Chemistry II, Vol 2 Chapter 2.5, 65 - 81 (2003).

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  13. Structural, luminescence, and NMR studies of the reversible binding of acetate, lactate, citrate, and selected amino acids to chiral diaqua ytterbium, gadolinium, and europium complexes, R.S. Dickins, S. Aime, A.S. Batsanov, A. Beeby, M. Botta, J. Bruce, J.A.K. Howard, C.S. Love, D. Parker, R.D. Peacock and H. Puschmann, J.Amer. Chem. Soc, 2002, 124, 12697 - 12705.

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  14. Survey of factors determining the circularly polarised luminescence of macrocyclic lanthanide complexes in solution, J.I Bruce, S. Lopinski, D. Parker and R. D. Peacock, Chirality, 2002, 14, 562-567.

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  15. X-ray Natural Circular Dichroism - Introduction and first results, R. D. Peacock in Chirality: Physical Chemistry, ed J. Hicks, ACS Symposium Series 810, pp 157-170, 2002.

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  16.  The synthesis of small azamacrocycles bearing pendant aromatic functionalities. - The crystal structures of [Cu(L1)2](PF6)2, [(L1)CuCl2], [Cu(L6)(NO3)2] and [Cu2(L7-H)2(OH2)2](PF6)2.3H2O (L1=N-(mesitylethyl)-1,4,7-triazacyclononane,L6=N-(4-hydroxymethylbenzyl)-1,4,7-triazacylcononane, L7=N-(4-benzylcarboxylic acid)-1,4,7-triazacylcononane), A. C. Bennison, D. Ellis, L. J. Farrugia, R. Kennedy, R. D. Peacock, and S. Walker, Polyhedron, 2002, 21, 333-342.


  17. Natural Circular Dichroism in X-ray Spectroscopy, R. D. Peacock and B. Stewart, J Phys Chem, 2001, 105, 351-360.(Invited Feature Article)

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  18.  Chiroptical, ESMS and NMR spectroscopic study of the interaction of enantiopure lanthanide complexes with selected self-complementary dodecamer oligonucleotides, G. Bobba, R.S. Dickins, S.D. Kean, C.E. Mathieu, D. Parker, R.D. Peacock, G. Siligardi, M.J. Smith, J.A.G. Williams and C.F.G.C. Geraldes, Perkin 2, 2001, 1729-1737.

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  19.  Fixing Carbon Dioxide with Copper: Crystal structure of [LCu(m-C4O4)Cu][Ph4B]2 (L = N, N’, N"- triallyl-1,4,7-triazacyclononane), L. J. Farrugia, S. Lopinski, P. A. Lovatt and R D Peacock, Inorg Chem, 2001, 40, 558 -559.

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  20.  Lanthanide Complexes of 2,2'-oxydiacetate: Na5[M(C4H4O5)3](BF4)2.6H2O   (M = Nd, Sm  or Gd), L.J. Farrugia R.D. Peacock and B. Stewart, Acta. Crystallog., 2000, C56, e435 - e436.

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  21. The Selectivity of Reversible Oxy-Anion Binding in Aqueous Solution at a Chiral Europium and Terbium Center: Signaling of Carbonate Chelation by Changes in the Form and Circular Polarization of Luminescence Emission,  J. I. Bruce, R. S. Dickins, L. J. Govenlock, T. Gunnlaugsson, S. Lopinski, M. P. Lowe, D. Parker, R. D. Peacock, J. J. B. Perry, S. Aime and M. Botta, J Amer. Chem. Soc, 2000, 112, 9674 - 9684.

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  22. A general route for the synthesis of triazacyclononane functionalised with one, two or three pendant phosphine arms - crystal structures of [NiL1Cl(HOEt)][ClO4] and [NiL1(NCS)2], L1 = N-(diphenyl -phosphinopropyl)-1,4,7-triazacyclononane, D. Ellis, L. J. Farrugia, P. A. Lovatt and R D Peacock, Eur J Inorg Chem, 2000, 1489.

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  23. Redetermination of the structure of the double salt {2L-[Co(en)3]Cl3.NaCl.H2O}, L.J. Farrugia, R D Peacock and B Stewart, Acta Crystallog. C., 2000, C56, 149.

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  24. Syntheses, Crystal Structures and CD Spectra of Simple Heterobimetallic Transition Metal Binaphtholates., R.J. Cross, L.J. Farrugia, D.R. McArthur, R D Peacock and D.S.C. Taylor,Inorg Chem, 1999, 38, 5698.

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  25. Chiroptical features and luminecent behaviour of macrocyclic tetra-(4-quinoyl)complexes: surprising absence of exciton coupling, L.J. Govenlock, J.A.K. Howard, J.M. Moloney, R D Peacock, D. Parker and G. Siligardi, Perkin 2, 1999, 2415.

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  26. Circular Dichroism at the edge - Large X-ray Natural CD in the 1s ® 3d pre-edge feature of 2[Co(en)3Cl3].NaCl.6H2O, B. Stewart, R D Peacock, L. Alagna, T. Prosperi, S. Turchini, J. Goulon, A. Rogalev, C. Goulon-Ginet, , J. Amer. Chem. Soc., 1999, 141, 10233.

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  27. Chiral phosphinoyl alcohol complexes of monoxobis(peroxo)molybdenum(VI) and their use as asymmetric oxidants, R J Cross, P D Newman, R D Peacock and D Stirling, J Mol Catal, 1999, , 144, 273.

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  28. N,N',N"-1,4,7-triazacyclononane with pendant alkyne arms: Crystal structures of [CuL'2][PF6]2, [NiL'2][ClO4]2 and CuL"Cl2 (L' = N-(4-but-2-yne)-1,4,7-triazacyclononane, L" = N-(5-pent-2-yne)-1,4,7-triazacyclononane), D. Ellis, L.J. Farrugia and R D Peacock, Polyhedron, 1999, 18, 1229.

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  29. Metal Complexes of New Chiral N2O2 Tetradentate Ligands and their Use as Asymmetric Oxidation Catalysts, R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, Inorg Chem, 1999, 38, 1186.

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  30. Stereochemical Synthesis and Crystal Structure of (+)-1S-Benzyl-1-(diphenylphosphoryl)propionic Acid, R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, Phosphorus, Sulphur, Silicon & related elements, 1998, 140, 63.

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  31. Redox reactions between molybdenum or tungsten hexafluorides and p, f or d block elements in acetonitrile. Comparison with reactions involving nitrosonium fluorometallates, the effect of fluoride ligand transfer and redox inhibition due to surface oxide, S I Ajiboye, J Iqbal, R D Peacock, N Prouff, G J Taylor, J M Winfield and X Liu, J Fluorine Chem, 1998, 91, 213.

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  32. Chiral Schiff base complexes of Copper(II), Vanadium(IV) and Nickel(II) as oxidation catalysts. X-ray structures of [Cu(R-salpen)(OH2)] and [Cu(+/-busalcx)], S Bunce, R J Cross, L J Farrugia, S Kunchandy, L L Meason, K W Muir, M O'Donnell, R D Peacock, D Stirling and S Teat, Polyhedron, 1998, 17, 4179.

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  33. Ground and excited state chiroptical properties of enantiopure macrocyclic tetranaphthyl lanthanide complexes: a chiral modulator?, R S Dickins, J A.K. Howard, C L Maupin, J Moloney, D Parker, R D Peacock, J P Reil and G Siligardi, New J of Chem, 1998, 891.

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  34. C-C coupling reactions on a flexible Ru3Pt framework: X-ray crystal structures of Ru3 Pt[(m4-C(But).C(H).C{C(But)}{C(H).C(But)}]{m-s-p-C(H)=C(H)-(But)}(CO)7(dppe), Ru3 Pt[(m3-C(But).C.C(But).CH2](CO)8(dppe) and Ru3Pt{(m4-C(Ph).C.C.C(H)(But)}((m4-Te)((m-TePri)(CO)6(dppe), L J Farrugia and N McDonald and R D Peacock, Polyhedron, 1998, 17, 2877.

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  35. Reversible anion binding in aqueous solution at a cationic heptacoordinate lanthanide centre: selective bicarbonate sensing by time-delayed luminescence, R S Dickens, T Gunnlaugsson, D Parker and R D Peacock, Chem Comm, 1998, 1643.

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  36. X-Ray Circular Dichroism, L Alagna, J Goulon, C Goulon-Ginet, C R Natoli, R D Peacock, T Prosperi, A Rogalev, B Stewart and S Turchini, Phys Rev Letters, 1998, 80, 4799 - 47802.

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Some Selected Publications from the PAST

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