1970 - 1979
1. R.
F. Jameson and R. D. Peacock,
A
Novel Preparation of Bis(4‑aminopent‑3‑en‑2‑onato)
nickel(II),
Journal of the Chemical Society (A), 2453 (1970).
2. R.
D. Peacock
Preparation
and Spectroscopic Investigation of Bis(acetylacetonato) copper(II),
Journal of Chemical Education, 48,
123‑124 (1971).
3. R.
D. Peacock
Hypersensitivity
of Spectral Bands in Complexes of Praesodymium(III),
Chemical Physics Letters, 7,
187 (1970).
4. J.
C. Barnes and R. D. Peacock
Hexanitrolanthanates(III),
Journal of the Chemical
Society (A),
558‑562 (1971)
5. R.
D. Peacock and T. J. R. Weakley
Heteropolytungstate
Complexes of the Lanthanide Elements Part I, Preparations and Reactions,
Journal of the Chemical Society (A), 1836‑1839 (1971).
6. R.
D. Peacock and T. J. R. Weakley
Heteropolytungstate Complexes of the
Lanthanide Elements Part II, ElectronicSpectra. A Metal‑to‑Ligand
Charge‑Transfer Transition of Ce(IV),
Journal of the Chemical Society (A), 1937‑1940 (1971).
7. R.
D. Peacock
Spectral Intensities of the Trivalent
Lanthanides Part I, The Solution Spectra of Heteropolycomplexes of
Praesodymium(III) and Holmium(III),
Journal of the Chemical Society (A), 1971, 2028‑2031 (1971).
8. R.
D. Peacock
A
Non‑vibronic Mechanism for the Hypersensitive Transition of
Europium(III),
Chemical Phyics. Letters, 10,
134‑135 (1971).
9. R.
D. Peacock
Spectral
Intensities of the Trivalent Lanthanides Part II, An Assessment of the
Vibronic Contribution,
Journal of the Chemical Society
Faraday Transactions II, 68, 169‑173 (1972).
10. J.
C. Barnes, C. S. Duncan and R. D. Peacock
Hexanitrite
Complexes, Part III, Electron Transfer
Spectra,
Journal of the Chemical Society
Dalton Transactions 1875‑1879
(1972).
11. R.
J. Dudley, S. F. Mason and R. D. Peacock
Infra‑red
Vibrational Circular Dichroism,
Journal of the Chemical Society
Chemical Communications, 1084‑1085 (1972).
12. R.
D. Peacock
The
Dependence of the Judd‑Ofelt Parameters on the Transitions Considered for
their Computation,
Chemical Physics Letters, 16,
590‑592 (1972).
13. S.F.
Mason and R.D. Peacock
Complexes
of Some First‑row Transition Elements with (‑)Spartein,
Journal of the Chemical Society
Dalton Transactions,
226‑228 (1973).
14 R.
D. Peacock
Spectral Intensities of the Trivalent
Lanthanides Part III, The Variation of the Judd‑Ofelt Parameters across
an Isostructural Series,
Molecular Physics, 25,
817‑823 (1973).
15. S.
F. Mason and R. D. Peacock
The
Location of the 1Lb Transition of Anthracene by Dichroism
Techniques,
Chemical Physics Letters, 21,
406‑408 (1973).
16. S.
F. Mason and R. D. Peacock
The
Optical Activity of Achiral Molecules in a Cholesteric Solvent,
Journal of the Chemical Society
Chemical Communications,
712‑713 (1973).
17. R.
D. Peacock
The
Solution Absorption Spectrum of Europium(III) in the Visible Region,
Journal of Chemical Physics, 61, 2483 (1974).
18. S.
F. Mason, R. D. Peacock and B. Stewart
Dynamic
Coupling Contributions to the Intensity of the Hypersensitive Lanthanide
Transitions,
Chemical Physics Letters, 29, 149‑153
(1974).
19. R.
J. Dudley, S. F. Mason and R. D. Peacock
The
Electronic and Vibrational Linear and Circular Dichroism of Nematic and
Cholesteric Systems,
Journal of the Chemical Society Faraday
Transactions II, 71, 997‑1007 (1975).
20. R.
D. Peacock
The
Intensities of Lanthanide f«f Transitions,
Structure and Bonding, 22,
83‑122 (1975).
21. R.
Gale, R. E. Godfrey, S. F. Mason, R. D. Peacock and B. Stewart
A
Complementation of the Crystal Field for Tetrahedral Intensities,
Journal of the Chemical Society
Chemical Communications,
329‑331 (1975).
22. R.
D. Peacock and B. Samori
The Polarisations of the Lowest Energy
Transitions of Pyridine‑1‑oxide and 4‑methylpyridine‑1‑oxide,
Journal of the Chemical Society
Faraday Transactions II, 71, 1909‑1911 (1975).
23. R.
D. Peacock
The
Polarised Absorption and Emission Spectrum of Eu3+ Doped in GdAl3(BO3)4,
Chemical Physics Letters, 35,
420‑422 (1975).
24. S.
F. Mason, R. D. Peacock and B. Stewart
Ligand
Polarisability Contributions to the Hypersensitive Transitions of the Trivalent
Lanthanides,
Molecular Physics,
30, 1829‑1841 (1975).
25. R.
Gale, R. D. Peacock and B. Samori
The
Linear Dichroism Spectra of Some Free‑base Porphyrins and their
Manganese(III) Derivatives,
Chemical Physics Letters, 27,
430‑432 (1976).
26. S.
F. Mason and R. D. Peacock
The
Ring Conformation d‑electron Optical Activity of a Cyclic Triamine
Cobalt(III) Complex,
Inorganica Chimica Acta, 19,
75‑77 (1976).
27. W.
G. Hill S. F. Mason and R. D. Peacock
The
Polarisations of the Near‑ultraviolet Band Systems of Disubstituted
Benzene Derivatives,
Journal of the Chemical Society Perkin Transactions II, 1262‑1278 (1977).
28. G.
Gottarelli, R. D. Peacock and B. Samori
The
Linear Dichroism of Organic Molecules in Electrically Oriented Liquid Crystal
Matrices,
Journal of the Chemical Society Perkin Transactions II, 1208‑1214 (1977).
29. S.F.
Mason, R. D. Peacock and T. Prosperi
The
Optical Resolution of Tris(pentane‑2,4‑dionato) Complexes of
Transition Metal Ions,
Journal of the Chemical Society
Dalton Transactions,
702‑704 (1977).
30. R.
D. Peacock
The
Charge‑transfer Contribution to the Intensity of Hypersensitive Trivalent
Lanthanide Transitions,
Molecular. Physics., 33,
1239‑1246 (1977).
31. R.
D. Peacock
The
Intensities of Laporte‑forbidden Transitions of the d‑block and f‑block
Transition Metal Ions,
Journal of Molecular Structure, 46, 203‑207 (1978).
32. R.
D. Peacock and B. Stewart
Hypersensitive
Intensity of the Pseudo‑octahedral Lanthanide Hexahalides,
Chemical Physics Letters, 55,
295‑296 (1978).
1980 –1989
33. A.
G. Lappin and R. D. Peacock
Slow
Electron Exchange at Tetrahedral Copper,
Inorganica Chimica Acta, 46,
L71‑72 (1980).
34. P.
J. Heaney, A. G. Lappin, R. D. Peacock and B. Stewart
Optical
Resolution and Circular Dichroism Spectrum of a Complex Containing Nickel(IV),
Journal of the Chemical Society Chemical Communications, 769‑770 (1980).
35. A.
F. Drake, R. Kuroda, S. F. Mason, R. D. Peacock and B. Stewart
The
d‑electron Optical Activity of Tetrahedral Dichloro‑[(‑)spartein]cobalt(II),
Journal of the Chemical Society
Dalton Transactions,
976‑980 (1981).
36. R.
D. Peacock and B. Stewart
The
Laser‑excited Emission Spectrum of Tetraphenyl‑phosphonium
Tetrathioperrhennate,
Chemical Physics Letters, 84,
300‑302 (1981).
37. R.
D. Peacock and B. Stewart
The Circularly Polarised Luminescence
Spectrum of [Cr(en)3]3+ in the Uniaxial Single Crystal
Host 2[Rh(en)3Cl3].NaCl.6H2O,
Journal of the Chemical Society
Chemical Communications,
295‑296 (1982).
38. R.
D. Peacock and B. Stewart
Circular
Dichroism of Transition Metal Complexes,
Co‑ordination Chemistry Reviews, 46, 129‑157 (1982).
39. R.
D. Peacock
Single Crystal Circular Dichroism
Spectra of Tris(pentane‑2,4‑dionato)cobalt(III) and tris(pentane‑2,4‑dionato)chromium(III),
Journal of the Chemical Society
Dalton Transactions,
291‑294 (1983).
40. A.
G. Lappin, M. C. M. Laranjeira and R. D. Peacock
Kinetics and Mechanism of the Reduction
of a Nickel(IV) Oxime‑imine Complex by[Co(edta)]‑.
Stereospecific Synthesis of a Stereoselective Oxidant,
Inorganic Chemistry, 22,
786‑791 (1983).
41. I.
F. Fraser and R. D. Peacock
Vibronic
Structure in the Luminescence Spectrum of Potassium Octachlorodimolybdate(II),
Chemical Physics Letters, 98,
620‑623 (1983).
42. P. S. Braterman, G. A.
Heath, A. J. Mackenzie, B. C. Noble, R. D. Peacock and L. J. Yellowlees
The Solution Structure and Properties
of [Ir(bipy)2‑(N,C‑C10H7N2)]2+
monohydrate "pseudo‑[Ir(bipy)3(OH)]2+",
Inorganic Chemistry, 23,
3425‑3426 (1984).
43 P.
A. Agaskar, F. A. Cotton, I. F. Fraser and R .D. Peacock
Configurational Chirality of Metal‑Metal
Multiple Bonds. Preparation and Circular Dichroism Spectrum of Tetra‑chlorobis(S,S)‑2,3‑(diphenylphosphino)butane‑
dimolybdenum, [Mo2Cl4(S,S‑dppb)2],
Journal of the American Chemical Society, 106, 1851‑1853
(1984).
44. R.
D. Peacock and B. Stewart
Degree of Circular Polarisation of
Resonance Raman Scattering ‑ Luminescence Discrimination and Assignment
of Non‑totally Symmetric Modes in [Ph4P][ReS4],
Journal of Raman Spectroscopy, 15,
396‑399 (1984).
45. I.
F. Fraser, A. McVitie and R. D. Peacock
Isomerisation Reactions of Quadruply‑bonded
Dimolybdenum Complexes containing
Diphosphine Ligands,
Journal of Chemical Research (S), 420‑421 (1984).
46. I.F.
Fraser and R. D. Peacock
Preparation and Circular Dichroism
Spectrum of the Tetrakis-(R)propane‑1,2‑diamino-
dimolybdenum cation {[Mo2(R‑pn)4]4+}. Evidence for a Bridged
Structure.
Inorganic Chemistry, 24,
989‑990 (1985).
47. R.D.
Peacock and B. Stewart
Electronic Absorption and Resonance
Raman Spectra of the [ReS4]‑ Ion ‑ Specific
Resonance Enhancement of Non‑totally Symmetric Modes,
Chemical Physics Letters, 120, 307‑312 (1985).
48. D.
P. Martone, P. Osvath, C. Eigenbrot, M. C. M. Laranjeira, A. G. Lappin and R.
D. Peacock
Stereoselectivity in Electron Transfer
Reactions. Determination of the Absolute Configuration of a Nickel(IV) Oxime‑imine
Complex,
Inorganic Chemistry, 24,
4693‑4699 (1985).
49. I.
F. Fraser and R.D. Peacock
Configurationally Chiral Dirhenium
Complexes with Triple and Quadruple Re‑Re Bonds: Preparation and Circular Dichroism of [Re2Cl4(S,S‑dppb)2] and [Re2Cl4(S,S‑dppb)2]2+,
Journal of the Chemical Society
Chemical Communications, 1727‑1728 (1985).
50. S.
Christie, I.F. Fraser, A. McVitie and R. D. Peacock
Isomerisation
Reactions of Some Diphosphine‑dimolybdenum Complexes,
Polyhedron, 5,
35‑37 (1986).
51. I.
F. Fraser, A. McVitie and R. D. Peacock
Circular
Dichroism of Configurally Chiral Dimolybdenum Complexes,
Polyhedron,
5, 39‑45 (1986).
52. P.
A. Agaskar, F. A. Cotton, I. F. Fraser, Lj. Manjlovic‑Muir, K. Muir and
R. D. Peacock
Syntheses, Structure and Circular Dichroism
Spectra of ß‑Mo2X4(S,S‑dppb)2; X = Cl, Br; S,S‑dppb = 2S,3S‑bis‑(diphenyphosphino)butane,
Inorganic Chemistry, 25,
2511‑2519 (1986).
53. P.S.
Braterman, B.C. Noble and R.D. Peacock
Circular
Dichroism Spectra of D‑[Ru(bipy)3]2+/+/0/‑,
Journal of Physical Chemistry, 90, 4913‑4915 (1986).
54. R.
D. Peacock
Optical
Activity of Quadruply Bonded Dimolybdenum and Dirhenium Complexes,
Polyhedron, 6,
715‑721 (1987).
(Invited
contribution to Polyhedron Symposium‑in‑Print No. 4; "Recent
Advances in
the
Chemistry of Metal‑Metal Multiple Bonds)
55. R.
D. Peacock and J. Robb
Preparation of the Chiral Hexadentate
Ligand N,N',N"‑tris[(S)‑2‑hydroxypropyl]
triazacyclononane and Preparation and Circular Dichroism Spectra of its Co(III)
Complexes,
Inorganica Chimica Acta, 121,
L13‑15 (19876).
56. I.
F. Fraser and R. D. Peacock
The
Excited State Geometry of [Re2Cl8]2‑,
Chemical Physics Letters, 137, 583‑586 (1987).
57. L.
J. Farrugia, A. McVitie and R. D. Peacock
Reaction of cis‑[Mo2(MeCO2)2(MeCN)6][BF4]2
with dmpe and S,S‑dppb:
Preparation, Crystal Structure and
Spectroscopic Properties of trans‑[Mo2(MeCO2)2(dmpe)2][BF4]2.
Inorganic Chemistry, 27,
1257‑1260 (1988).
58. T.J.
Dines and R. D. Peacock
Surface Enhanced Resonance Raman
spectroscopy of Iron(II) and Ruthenium(II) Bipyridyl Complexes Adsorbed on
Silver Sols,
Journal of the Chemical Society
Faraday I, 3445‑34457
(1988).
59.
A. Belal,
L.J. Farrugia, R. D. Peacock and J. Robb
Synthesis and Spectroscopic Studies of
Co(III) Complexes of the Chiral Pendant‑arm
Macrocycle N,N',N"‑tris[(2S)‑2‑hydroxypropyl]‑1,4,7‑triazacylcononane
(LH3); Crystal Structure of the Hydrogen‑bridged Dimer [CoLH3LCo][PF6]3,
Journal of the Chemical Society
Dalton Transactions,
931‑935 (1989).
60. G.
Haining, L. McGhee, R. D. Peacock, R. M. Siddique, S. H. Wang and J. M. Winfield
Macrocycle
Metal and Non‑metal Cations and Fluoro‑ anion Salts.
Journal of Fluorine Chemistry, 45, 49 (1989)
61. The
Intensities of Lanthanide spectra
Current Contents, 29,
15 (1989).
1990 - 1999
62. B.
C. Noble and R. D. Peacock
Spectroscopic
Studies of [Li][bipy]
Spectrochimica Acta, 46A,
407‑412 (1990)
63. L.
J. Farrugia and R. D. Peacock
Structure of N,N',N"‑tris[(2S)‑2‑hydroxypropyl]‑1,4,7‑triaza‑cyclononane
nickel(II) dibromide monohydrate.
Acta Crystallographica, C47, 1312‑1313 (1991).
64. L.J.
Farrugia, N. Macdonald and R. D. Peacock
Synthesis and Crystal Structure of [Ru3Pt(m‑PPh2)m4‑ h 2‑CşCtBu)(CO)7(dppe)],
a Butterfly Cluster Containing
an Unusually Bonded Alkynyl Ligand: A
Model for an Intermediate Geometry in a Cluster‑Ligand Rearrangement.
Journal of the Chemical Society
Chemical Communications,
163‑165 (1991).
65. A.
Belal, I. Fallis, L.J. Farrugia, N.M. Macdonald and R. D. Peacock
Synthesis and Crystal Structure of
[Mn(II)LH3LMn(IV)] [PF6]3 (LH3 =
tris‑(2S)‑2‑hydroxy-propyl‑
N,N',N"‑1,4,7‑triazacyclononane): a Mixed‑valence
Pendant‑arm Macrocycle dimer in which the Ligand
Adopts Different Angular Geometries at
the Two Metal Centres.
Journal of the Chemical Society
Chemical Communications,
402‑403 (1991).
66. S.
I. Ajiboye, J. R. Fryer, A. H. Fzea, R. D. Peacock and J. M. Winfield
Oxidising
Properties of Transition Metal Hexafluorides towards p‑Block Elements
and
Polymeric m‑Fluoro(Pthalocyanine)Aluminium(III).
Journal of Fluorine Chemistry, 54,
389 (1991).
67. R.
M. Awadallah, A. A. M. Belal, R. M. Issa and R. D. Peacock
The
Colours of Simple Salts of the Violurate Anion.
Spectrochimica. Acta, 47A, 1541‑1546
(1991).
68. A.
A. Aitchison, L. J. Farrugia and R. D.
Peacock
Structure
of ß‑[Mo2(NCS)4{2S,3S‑bis(diphenylphosphino‑butane}2]
(nitromethane solvent).
Acta Crystallographica, C47,
2556‑2558 (1991).
69.
L J
Farrugia, N Macdonald and R. D. Peacock
Structure of 1,2,2,3,3,4,4‑Heptacarbonyl‑
2,3;3;4‑ di‑m‑
carbonyl‑1,2‑m‑hydrido‑
2,4‑m‑3‑cyclooctenyl
‑1‑ tricyclohexylphosphine‑tetrahedro‑ platinum‑triruthenium.
Acta Crystallographica, C47,
2561‑2564 (1991).
70. A.
Bennett, S. Christie, M. A. Keane, R. D. Peacock and G Webb
The Enantioselective Hydrogenation of
Methylacetoacetate over Nickel Catalysts Modified with Tartaric Acid
Catalysis Today, 10,
363‑370 (1991).
71. A. Belal, P. Chaudhuri, I. Fallis,
L .J. Farrugia, R. Hartung, N. M.
Macdonald, B. Nuber, R. D.
Peacock J. Weiss and K. Wieghardt.
Synthesis, Structural and Spectroscopic
Studies of Manganese Complexes of Pendant‑arm Macrocycles Based on 1,4,7‑triazacyclononane:
Crystal Structures of the Mn(II) Complex [MnLH3][MnCl4]
and of the Mixed‑valence
Mn(II),Mn(IV) Hydrogen-bridged Dimer
[MnLH3LHMn][PF6]3.(LH3 = N,N',N"‑ tris[(2S)‑2‑ hydroxy-propyl]-
1,4,7‑triaza‑cyclo‑nonane)
and of the Mn(IV) Monomer [MnL'][ClO4](LH'3 = N,N',N"‑ tris- (2‑hydroxyethyl)‑
1,4,7‑triazacyclononane);
Inorganic Chemistry, 30, 4397‑4402 (1991).
72. P.
S. Braterman, J‑I. Song and R. D. Peacock
Electronic Absorption Spectra of the
Iron(II) Complexes of 2,2'‑Bipyrimidine, 1.10‑Phenanthroline and
2,2':6',2"‑Terpyridine and their Reduction Products.
Inorganic Chemistry, 31,
555‑559 (1992).
73. R.D. Peacock
Azide Hazard
Chemistry in Britain
28, 327 (1992)
74. P.
S. Braterman, J‑I. Song and R. D. Peacock
Spectroelectrochemistry and
Localisation of Added Electrons in Ruthenium(II) Mixed‑Ligand Complexes.
Spectrochimica Acta., 48A,
899 - 903 (1992).
75. A. McVitie and R. D. Peacock
Solid
State Studies of a and ß‑[Mo2Cl4(dppe)2]
‑ Kinetics of the a ® ß Isomerisation
and Solid State 13C and 31P NMR Spectra.
Polyhedron, 11, 2531 - 2536 (1992).
76. T.
Baird, P. S. Braterman, P. Cheng, R. D. Peacock J-M. Garcia Ruiz and A. Reid
Morphology of Gell-Grown Barium
Carbonate Aggregates - pH Effect on
Control by a Silicate-Carbonate Membrane.
Materials Research Bulletin, 27,
1031-1040 (1992).
77. P.
S. Braterman, R. D. Peacock, J-I. Song, F. M. Wimmer, S. Wimmer, W. Kaim and A. Klein
Electrochemistry and Spectroelectrochemistry
(EPR, uv-vis-nir) of 2,2'-Bipyridine and Ring-metallated Bipyridine Pt(II)
Complexes; Pt(II)(L-) and Pt(I)(L-) but not Pt(I)(L).
Inorganic Chemistry, 31,
5084-5088 (1992).
78. I.
F. Fallis, L. J. Farrugia, N. M. Macdonald and R. D. Peacock
Synthesis
of a Mixed‑metal, Hydrogen‑bridged dimer of the Pendant‑arm
Macrocyclic Ligand
N,
N',N"‑tris[(2S)‑2‑hydroxypropyl]‑1,4,7‑triazacyclononane),
LH3. Crystal Structure of [Zn(II)LH3LV(IV)][PF6]3.
a Complex containing Trigonal Zn(II) and
Non‑vanadyl V(IV).
Inorganic Chemistry, 32,
779-780 (1993).
79. M.
J. Edmiston and R. D. Peacock
A Surface Enhanced Raman Study of the
Adsorption of tris(2,2-bipyridine)
ruthenium(II) and Substituted
Analogues on Chemically-Deposited
Silver Films.
Spectrochimica Acta, 49A,
1481-1486 (1993).
80. L.
J. Farrugia, P. A. Lovatt and R. D.
Peacock
Structure
of [1,4,7-triazacyclo[5.2.1.04.10]decane-N-3-phenoxypropyl]bromide hydrate.
Acta Crystallographica C49,
2164-2165 (1993).
81. I. A. Fallis, L. J. Farrugia, N. M.
Macdonald and R. D. Peacock
Synthesis and co-ordination chemistry
of the sterically demanding pendant arm macrocycle N,N',N''‑tris‑[(2R)-2‑hydroxy‑3‑
methyl‑butyl]‑ 1,4,7‑triazacyclononane.
Journal of the Chemical Society
Dalton Transactions,
2759-2763 (1993).
82. H.
El‑Sagher, I. A. Fallis, L. J. Farrugia and R. D. Peacock
Trigonal
Prismatic Geometry With Non‑rigid Ligands: Cobalt(II) Complexes of
Triazamacrocycles
with Pendant
Alcohol Arms,
Journal of the Chemical Society Chemical
Communications,
1499-1500 (1993).
83. A.
A. M. Belal, A. H. Amrallah and R. D. Peacock
Determination of Stepwise Formation
Constants of MnII, FeII, FeIII, CoII
and CuII Chelates with 1,4,7-N,N’,N”-triazacyclononane.
Asian Journal of Chemistry, 6,
164-168 (1994).
84. B.
C. Noble and R. D. Peacock
Absorption
and Circular Dichroism Spectra of D-[Os(bipy)3]2+\+\0\-
Spectrochimica Acta, 50A, 1777-1781 (1994).
85. A.
G. Comrie, A. McVitie and R. D. Peacock
Preparation
and Spectroscopic Characterisation of the Elusive Octammine- dimolybdenum
Cation:
[Mo2(NH3)8][TFMS]4.
Polyhedron, 13,
193-197 (1994).
86. L.
J. Farrugia, N. McDonald and R. D. Peacock
Further studies on the tautomerisation
of the hydrido (alkynyl) cluster Ru3Pt(m-H){m4-h2-CşCtBu} (CO)9(L2)
to the vinylidine cluster Ru3Pt{m4-h2-C=(H)CtBu}(CO)9(L2):
X-ray structures of Ru3Pt(m-H){m4-h2-CşCtBu}(CO)9(dppet)
and Ru3Pt{m4-h2-C=(H)CtBu}(CO)9(L2); L2 =
dppet, dppp and S,S-dppb.
Journal of Cluster Science, 5,
341-361 (1994).
87. L.
J. Farrugia, N. M. Macdonald, R. D. Peacock
and J. Robb
Crystal Structure of the Hydrogen‑bridged
Dimer [CrLH3LCr][PF6]3, (LH3 = N,N',N"‑tris[(2S)‑2‑hydroxy‑ propyl]‑1,4,7‑triazacyclononane)
Polyhedron, 14,
451-455 (1995).
88. S-H.
Wang, S. I. Ajiboye, G. Haining, L. McGhee, G. Peattie, R. M. Siddique, R. D.
Peacock and J. M. Winfield
Coordination
Chemistry of Iodine(I) with Tetraazamacrocycles or Monodentate Ligands.
Comparison
with
Bromine(I) and some d Block Metals.
Journal of the Chemical Society
Dalton Transactions,
3837-3841 (1995).
89. T.
Baird, A. G. Cairns-Smith, R. D. Peacock, B. Stewart and G. Turner
Layer
Morphology and Growth Mechanism in Barium Ferrites.
Journal of Crystal Growth, 158,
276-283 (1996).
90. M.
J. Edmiston and R.D. Peacock
Surface Enhanced Resonance Raman
Spectroscopy of tris(2,2’-bipyridine) ruthenium(II) and substituted analogues
on novel vapour deposited surfaces.
Spectrochemica Acta A,
52A, 191-198 (1996).
91. L.
J. Farrugia, P. A. Lovatt and R.D. Peacock
Macrocycles
with a Single Pendant Arm: Synthesis of N-R-(1,4,7-triazacyclononane)
(L,
R = 4-but-1-ene; L', R = 3-prop-1-ene). Synthesis of the CuI complex
[CuL]I and synthesis
and
crystal structure of the CuII complex [CuL2][BPh4]2
and the m-hydroxy bridged CuII dimer
[LCu(m-OH)2CuL][BPh4]2.
Inorganica Chimica Acta, 246,
343-346 (1996).
92. R.
J. Cross, L. J. Farrugia, P. D. Newman, R.D. Peacock and D Stirling
2-(Diphenylphosphinyl)propanoate
complexes: Crystal structure of tris[2-(Diphenylphosphinyl)
propanoato]vanadium(III)
Journal of the Chemical Society
Dalton Transactions,
1087-1092 (1996)
93. B.C.
Noble and R.D. Peacock
Absorption, Circular Dichroism,
Luminescence and Infra‑red Spectroscopy of Chemically and
Electrochemically
Reduced Ru(II) and Os(II) Bipyridyl
Complexes.
Inorganic Chemistry, 35, 1616-1620 (1996)
94. G.
Smith, P. R. Mallinson, R.D. Peacock,
L. J. Farrugia, I. A. Fallis, C. S. Frampton and J. A. K. Howard
Experimental
Determination of the Electron Configuration of the Nickel Ion in a
Complexed Macrocycle by X-ray Diffraction.
Journal of the Chemical Society Chemical Communications, 525-526 (1996)
95. R
J Cross, L J Farrugia, P D Newman, R.D. Peacock and D Stirling
Metal Complexes of Chiral
Phosphinylalkoxide Ligands: Crystal Structure of
Bis[1S-methyl-2-(diphenylphosphinyl)ethanolato]dichlorotitanium(IV).
Journal of the Chemical Society
Dalton Transactions , 1637-1643 (1996)
96. C.F.
Scott, L. J. Farrugia and R.D. Peacock
Structure
of the Naphthofuranquinone Dinaphtho[2,1-b.2’,3’-d]furan-8-13-dione
Acta Crystallographica C,
C52, 1310-11 (1996)
97. R
J Cross, L J Farrugia, P D Newman, R.D. Peacock and D Stirling
Attempted resolution and chiral
synthesis of 2-(Diphenylphosphinyl)propanoic acid: crystal structure of 1R,2S,5R-menthyl-2S-(Diphenylphosphinyl)propanoate
Journal
of Chemical Research(S),
222-223 (1996): Journal of Chemical
Research(M), 1227-1250 (1996).
98. C.M.
Lindall, J. A. Crayston, D. J. Cole-Hamilton, A. Glidle and R.D. Peacock
Preparation and Electrochemical Quartz
Crystal Microbalance Characterisation of [Os(bipy)2(PVPS)nClRu(edta)]
Redox Polymers
Journal of Materials Chemistry, 1259-1269 (1996).
99. D Ellis, L J Farrugia, D T Hickman, P A Lovatt and R.D. Peacock
A general route for the synthesis of triazacyclononane functionalised with one, two or three pendant phosphine arms –
crystal structure of [Zn2L2Cl3][ClO4], L = N-(diphenyl-phosphinopropyl)-1,4,7-triazacyclononane.
Chemical Communications, 1817-1818 (1996).
100. R. J. Cross, L. J. Farrugia, P. D. Newman, R.D. Peacock and D.
Stirling
R and S-2-(diphenylphosphinoyl)-2’-hydroxy-1-1’-dinaphthalene: versatile chiral bidentate ligands.
Journal of the Chemical Society
Dalton Transactions , 4449 - 4458 (1996).
101. R.
J. Cross, L. J. Farrugia, P. D. Newman, R.D. Peacock and D. Stirling
Camphor-based
b-hydroxyphosphorylligands and complexes of the
type [MoO(O2)(L)(OH)2]
Journal of the Chemical Society
Dalton Transactions 4149-4150 (1996).
102. R.
S. Dickens, J. A. K. Howard, C. W. Lehmann, J. Moloney, D. Parker and R. D. Peacock
Structural
rigidity and chiral luminescence of lanthanide tetra-amide complexes based
on
1,4,7,10-tetraazacyclododecane.
Angewandte Chemie
International Edition English, 36, 521 - 523 (1997)
103. L J Farrugia, P A Lovatt and R.D. Peacock
Synthesis of a Series of Novel Binucleating Ligands based on 1,4,7-triazacyclononane and o,m and p-xylene:
Crystal Structure of the m-Hydroxy-bridged Di-copper(II) Complex [Cu2Lm(OH)2][BPh4]2 ;
Lm = Bis-a,a‘-(N-1,4,7-triazacyclononane)-m-xylene.
Journal of the Chemical Society Dalton Transactions, 911 - 913 (1997).
104. G.
Smith, P. R. Mallinson, C. R. Frampton, L. J. Farrugia, R. D. Peacock, and J. A. K. Howard
Experimental
determination of the electron density topology of a non-centrosymmetric
transition
metal complex -[Ni(H3L)][NO3][PF6]; H3L
= N,N',N''‑tris‑[(2R)2‑hydroxy‑3‑
methyl‑butyl]‑
1,4,7‑triazacyclononane.
Journal of the American
Chemical Society, 119, 5028 - 5034 (1997)
105.L. Alagna, J. Goulon, C.
Goulon-Ginet, T. Prosperi, A. Rogalev, R.D. Peacock, B. Stewart and S.
Turchini
Natural Circular Dichroism at the Nd L3 Edge in Single Crystals of
Na3Nd(C4H4O5)3.2NaBF4
6H2O
Journal de Physique IV, 7, Colloque C2, 463-4 (1997).
106. R
S. Dickins, J. A.K. Howard, J. Moloney, D. Parker, R.D. Peacock and G.
Siligardi
Strong Exciton Coupling and Circularly Polarised Luminescence in Rigid
Complexes of Chiral
Macrocyclic Tetra-naphthylamides.
Chemical Communications,
1747 - 8 (1997).
107. L.
McGhee, I. Nicol, R.D. Peacock, M. I. Robertson, P. R. Stevenson and J. M.
Winfield
Halogen Etching of 13-15 semiconductors
and its Relevance to Chemomechanical Polishing. The reactions of dibromine,
dichlorine and sodium hypochlorite with gallium arsenide and related materials.
Journal of Materials Chemistry, 7, 2421 - 6 (1997)
108. L.
Alagna, J. Goulon, C. Goulon-Ginet, C. R. Natoli, R.D. Peacock T. Prosperi, A.
Rogalev, B.
Stewart and S. Turchini
X-Ray
Circular Dichroism
Physical Review Letters, 80,
4799- 4802 (1998).
109. R.
S. Dickens, T. Gunnlaugsson, D. Parker and R. D. Peacock
Reversible anion binding in aqueous
solution at a cationic heptacoordinate lanthanide centre: selective bicarbonate sensing by time-delayed
luminescence.
Chemical Communications,
1643-1644 (1998)
110.L J Farrugia, N McDonald and R.D.
Peacock,
C-C
coupling reactions on a flexible Ru3Pt framework: X-ray crystal
structures of
Ru3Pt[m4-C(But).C(H).C{C(But)}{C(H).C(But)}]{m-s-p-C(H)=C(H)-(But)}(CO)7(dppe),
Ru3Pt[m3-C(But).C.C(But).CH2](CO)8(dppe)
and Ru3Pt{m4-C(Ph).C.C.C(H)(But)}(m4-
Te)(
m-TePri) (CO)6 (dppe).
Polyhedron,
17, 2877 (1998).
111. R
S Dickins, J A.K. Howard, C L Maupin, J Moloney, D Parker, R.D. Peacock, J P Reil and G
Siligardi
Ground
and excited state chiroptical properties of enantiopure macrocyclic
tetranaphthyl
lanthanide
complexes: a chiral modulator?
New Journal of Chemistry,
891 (1998).
112. S
Bunce, R J Cross, L J Farrugia, S Kunchandy, L L Meason, K W Muir, M
O’Donnell,
R.D. Peacock, D Stirling and S Teat,
Chiral
Schiff base complexes of Copper(II), Vanadium(IV) and Nickel(II) as oxidation
catalysts.
X-ray structures of [Cu(R-salpen)(OH2)] and [Cu(+/-busalcx)].
Polyhedron,
17, 4179 (1998).
113.S I Ajiboye, J Iqbal, R.D. Peacock,
N Prouff, G J Taylor, J M Winfield and X Liu,
Redox reactions between molybdenum or
tungsten hexafluorides and p, f or d block elements in acetonitrile. Comparison
with reactions involving nitrosonium fluorometallates, the effect of fluoride
ligand transfer and redox inhibition due to surface oxide.
Journal of Fluorine Chemistry, 91, 213 (1998).
114. R
J Cross, L J Farrugia, P D Newman, R.D. Peacock and D Stirling,
Stereochemical Synthesis and Crystal Structure of
(+)-1S-Benzyl-1-(diphenylphosphoryl)propionic Acid.
Phosphorus, Sulphur, Silicon &
related elements, 140,
63-72 (1998).
115. R
J Cross, L J Farrugia, P D Newman, R.D. Peacock and D Stirling,
Metal
Complexes of New Chiral N2O2 Tetradentate Ligands and
their Use as
Asymmetric
Oxidation Catalysts.
Inorganic Chemistry,
38, 1186 (1999).
116. D. Ellis, L.J. Farrugia and R.D. Peacock,
N,N’,N”-1,4,7-triazacyclononane with pendant alkyne arms: Crystal structures of [CuL’2][PF6]2, [NiL’2][ClO4]2 and CuL”Cl2 (L’ = N-(4-but-2-yne)-1,4,7-triazacyclononane, L” = N-(5-pent-2-yne)-1,4,7-triazacyclononane).
Polyhedron, 18, 1229-1234 (1999).
117. R
J Cross, P D Newman, R.D. Peacock and D Stirling,
Chiral phosphinoyl
alcohol complexes of monoxobis(peroxo)molybdenum(VI) and their
use
as asymmetric oxidants.
Journal of Molecular Catalysis, 144, 273-284 (1999).
118. R.J. Cross, L.J. Farrugia, D.R. McArthur, R.D. Peacock and D.S.C. Taylor
Synthesis, Crystal Structures and CD Spectra of Simple Heterobimetallic Transition Metal
Binaphtholates.
Inorganic Chemistry, 38, 5698 - 5702 (1999).
119.B. Stewart, R. D. Peacock, L. Alagna, T. Prosperi, S. Turchini, J. Goulon, A. Rogalev and C. Goulon-Ginet
Circular Dichroism at the edge - Large X-ray Natural CD in the 1s ® 3d pre-edge feature
of 2[Co(en)3Cl3].NaCl.6H2O.
Journal of the American Chemical Society, 141, 10233-34 (1999).
120.L.J. Govenlock, J.A.K. Howard, J.M. Moloney,
R.D. Peacock, D. Parker and G. Siligardi,
Chiroptical features and luminecent
behaviour of macrocyclic tetra-(4-quinoyl)complexes: surprising absence of
exciton coupling.
Journal of the Chemical Society
Perkin 2, 2415-6 (1999).
2000 - 2009
121. D. Ellis, L. J. Farrugia, P. A. Lovatt and R.D. Peacock,
A general route for the synthesis of triazacyclononane functionalised with one, two or three pendant
phosphine arms - crystal structures of [Zn2L12Cl3][ClO4], [NiL1Cl(HOEt)][ClO4] and [NiL1(NCS)2],
L1 = N-(diphenylphosphinopropyl)-1,4,7-triazacyclononane.
European Journal of Inorganic Chemistry, 1489 - 1493 (2000).
122. L.J. Farrugia, R.D. Peacock and B. Stewart,
Redetermination of the structure of the double salt {2L-[Co(en)3]Cl3.NaCl.H2O}.
Acta Crystallographica. C, C56, 149 - 151 (2000).
123. J. I. Bruce, R. S. Dickins, L. J. Govenlock, T. Gunnlaugsson, S. Lopinski, M. P. Lowe, D. Parker, R. D. Peacock, J. J. B. Perry, S. Aime, and Mauro Botta
The Selectivity of Reversible Oxy-Anion Binding in Aqueous Solution at a Chiral
Europium and Terbium Center: Signaling of Carbonate Chelation by Changes in
the Form and Circular Polarization of Luminescence Emission.
Journal of the American Chemical Society, 112, 9574 - 9684 (2000).
124. L.J. Farrugia, R.D. Peacock and B. Stewart,
Lanthanide Complexes of 2,2'-oxydiacetate: Na5[M(C4H4O5)3](BF4)2.6H2O (M = Nd, Sm or Gd)
Acta Crystallographica. C, C56, e435 - e436 (2000).
125. R. D. Peacock and B Stewart
Circular Dichroism in the X-ray Region.
Journal of Physical Chemistry, 105, 351-360 (2001).
(invited "feature" article)
126. L. J. Farrugia, S. Lopinski, P. A. Lovat and R.D. Peacock,
Fixing Carbon Dioxide with Copper: Crystal structure of [LCu(m-C4O4)Cu][Ph4B]2 (L = N, N’, N”-
triallyl-1,4,7-triazacyclononane),.
Inorganic Chemistry, 40, 558-559 (2001).
127. G. Bobba, R.S. Dickins, S.D. Kean, C.E. Mathiew, D. Parker, R.D. Peacock, G. Siligardi, M.J. Smith, J.A.G. Williams and C.F.G.C. Geraldes
Chiroptical, ESM and NMR spectroscopic study of the interaction of enantiopure lanthanide complexes with selected self-complementary dodecamer oligonucleotides
Journal of the Chemical Society Perkin 2, 1729 - 1737 (2001)
128.A. C. Benniston, D. Ellis, L. J. Farrugia, R. Kennedy, R. D. Peacock, and S. Walker,
The synthesis of small azamacrocycles bearing pendant aromatic functionalities. - The crystal structures of [Cu(L1)2](PF6)2, [(L1)CuCl2], [Cu(L6)(NO3)2] and [Cu2(L7-H)2(OH2)2](PF6)2.3H2O
(L1=N-(mesitylethyl)-1,4,7-triazacyclononane, L6=N-(4-hydroxymethylbenzyl)-1,4,7-triazacylcononane, L7=N-(4-benzylcarboxylic acid)-1,4,7-triazacylcononane)
Polyhedron, 21, 333-342 (2002)
129.R. D. Peacock
X-ray Natural Circular Dichroism - Introduction and First Results
in Chirality - Physical Chemistry (ACS Symposium Series 810), ed J Hicks, Oxford University Press, 157-170 (2002)
130.J.I Bruce, S. Lopinski, D. Parker and R. D. Peacock,
Survey of factors determining the circularly polarised luminescence of macrocyclic lanthanide complexes in solution.
Chirality,
14, 562-567 (2002).
131. R.S. Dickens, S. Aime, A.S. Batansov, A. Beeby, M. Botta, J.I.
Bruce, J.A.K. Howard, C.S. Love,
D. Parker, R.D.
Peacock and H. Puschmann,
Structural, luminescence and NMR studies of the reversible binding of acetate, lactate, citrate and selected amino-acids to chiral di-aqua Ytterbium, Gadolinium and Europium complexes.
Journal of the American
Chemical Society,
124,
12697 – 12705 (2002).
132. R.D. Peacock and B. Stewart,
“Chiral Spectroscopy” in
Comprehensive Coordination Chemistry II, Elsevier, (2003)
133. S. Turchini, N. Zema, L.
Alagna, B. Stewart, R.D. Peacock and T. Prosperi,
Core electron Transitions as a
probe for molecular chirality – Natural Circular Dichroism at the carbon K-edge of methyloxirane.
Journal of the American Chemical Society, 126, 4532 - 4533 (2004).
134. P. Gunning, A,C, Benniston
and R.D. Peacock,
A
Modular Ditopic Crown-Shielded Phosphate Ion Pair Receptor
Chemical. Communications. 2226-2227 (2004)
135. P. Gunning, A,C, Benniston
and R.D. Peacock,
Synthesis
and Binding Prpperties of Hybrid Cyclophane-Axomacrocyclic Receptors.
Journal of Organic
Chemistry, 70,
115-123. (2005)
136. R.
A. Poole, G. Bobba, M. J. Cann,
J-C. Frias, D. Parker and R. D. Peacock,
Synthesis and characterisation of highly emissive and kinetically stable lanthanide complexes suitable for usage “in cellulo”,
Organic and Biomolecular Chemistry, 3, 1013-1024 (2005)
137. L. J. Farrugia, C. S. Frampton, J. A. K. Howard, P. R. Mallinson, R. D. Peacock, G. T. Smith, and B.
Stewart
Experimental Charge Density Study on the Ni(II) Coordination Complex [Ni(H3L)][NO3][PF6] [H3L = N,N˘,N˘˘-Tris(2-hydroxy-3-methylbutyl)-1,4,7-triazacyclononane : A Reappraisal.
Acta Crystallographica B, 62. 236-244 (2006)
138. J.P. Leonard, P. Jensen, T. McCabe,
J.E. O’Brian, R,D,Peacock, P.E. Kruger and
T. Gunnlaugsson
Self-assembly
of Chiral Luminescent Lanthanide Co-ordination Bundles.
Journal of the American Chemical Society, 129, 10986-10987 (2007).
139. R. D. Peacock, T. Prosperi and B. Stewart
Orthoaxial Single Crystal X-ray Circular and Linear
Dichroism of the 1s ® 3d
transition of {L-
[Co(en)3]Cl3}2.NaCl.6H2O:
measurement of the absolute values of the quadupole and dipole
contributions to the intensity of a
pre-edge transition.
Chemical Physics Letters, 444, 375-378 (2007).
140. R. D. Peacock
and B. Stewart,
Emeritus Professor Stephen Mason (obituary)
RSC News, March 2008, p22.
(fuller version at http://www.rsc.org/obituaries)
141. K. W. Galloway, A. M. Whyte, W. Wernsdorfer, J. Sanchez-Benitez, K. V. Kamenev, A. Parkin, R. D.
Peacock and M. Murrie
A Cobalt(II) Citrate Cubane Single-Molecule Magnet
Inorganic Chemistry,
47, 7438-7442 (2008).
142. C.P. Montgomerie, E.J. New,
D. Parker and R.D. Peacock
Enantioselective regulation of a metal complex in
reversible binding to serum albumin: dynamic
helicity inversion signaled by circularly polarized
luminescence.
Chemical Communications., 2461-2463 (2008)
143. C. Ritchie, C. Streb, J. Thiel, S. G. Mitchell, H. N. Miras, D-L. Long, T. Boyd, R. D. Peacock,
T. McGlone, and L. Cronin
Reversible redox reactions in an
extended polyoxometalate framework solid
Angewandte
Chemie International Edition English, 47, 6881-6884 (2008)
144. E.J. New, D. Parker and R.D. Peacock ,
Comparative study of the constitution and chiroptical properties of emissive terbium and europium
complexes with a common tetraazatriphenylene sensitiser; the nature of the sensitiser determines
quenching sensitivity and cellular uptake
Dalton Transactions, 672-679 (2009)
145. F. Stomeo, C.
Lincheneau, J.
P. Leonard, J. E. O’Brien,
R. Peacock, C. P. McCoy and T. Gunnlaugsson
Metal
directed synthesis of enatiomerially pure dimetallic lanthanide luminescent
triple-stranded helicates
Journal of the American Chemical
Society, submited
.
.