R. D. PEACOCK - RECENT PUBLICATIONS (1996 - 2001)

  1. X-ray Natural Circular Dichroism - Introduction and first results, R. D. Peacock in The Physical Chemistry of Chirality, ed J. Hicks, Oxford, in press (April 2001).

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  2. Natural Circular Dichroism in X-ray Spectroscopy, R. D. Peacock and B. Stewart, J Phys Chem, 2001, 105, 351-360.(Invited Feature Article)

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  3.  Fixing Carbon Dioxide with Copper: Crystal structure of [LCu(m-C4O4)Cu][Ph4B]2 (L = N, N’, N"- triallyl-1,4,7-triazacyclononane), L. J. Farrugia, S. Lopinski, P. A. Lovatt and R D Peacock, Inorg Chem, 2001, 40, 558 -559.
  4.  Lanthanide Complexes of 2,2'-oxydiacetate: Na5[M(C4H4O5)3](BF4)2.6H2O   (M = Nd, Sm  or Gd), L.J. Farrugia R.D. Peacock and B. Stewart, Acta. Crystallog., 2000, C56, e435 - e436.

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  5. The Selectivity of Reversible Oxy-Anion Binding in Aqueous Solution at a Chiral Europium and Terbium Center: Signaling of Carbonate Chelation by Changes in the Form and Circular Polarization of Luminescence Emission,  J. I. Bruce, R. S. Dickins, L. J. Govenlock, T. Gunnlaugsson, S. Lopinski, M. P. Lowe, D. Parker, R. D. Peacock, J. J. B. Perry, S. Aime and M. Botta, J Amer. Chem. Soc, 2000, 112, 9674 - 9684.

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  6. A general route for the synthesis of triazacyclononane functionalised with one, two or three pendant phosphine arms - crystal structures of [NiL1Cl(HOEt)][ClO4] and [NiL1(NCS)2], L1 = N-(diphenyl -phosphinopropyl)-1,4,7-triazacyclononane, D. Ellis, L. J. Farrugia, P. A. Lovatt and R D Peacock, Eur J Inorg Chem, 2000, 1489.

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  7. Redetermination of the structure of the double salt {2L-[Co(en)3]Cl3.NaCl.H2O}, L.J. Farrugia, R D Peacock and B Stewart, Acta Crystallog. C., 2000, C56, 149.

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  8. Syntheses, Crystal Structures and CD Spectra of Simple Heterobimetallic Transition Metal Binaphtholates., R.J. Cross, L.J. Farrugia, D.R. McArthur, R D Peacock and D.S.C. Taylor,Inorg Chem, 1999, 38, 5698.

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  9. Chiroptical features and luminecent behaviour of macrocyclic tetra-(4-quinoyl)complexes: surprising absence of exciton coupling, L.J. Govenlock, J.A.K. Howard, J.M. Moloney, R D Peacock, D. Parker and G. Siligardi, Perkin 2, 1999, 2415.

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  10. Circular Dichroism at the edge - Large X-ray Natural CD in the 1s ® 3d pre-edge feature of 2[Co(en)3Cl3].NaCl.6H2O, B. Stewart, R D Peacock, L. Alagna, T. Prosperi, S. Turchini, J. Goulon, A. Rogalev, C. Goulon-Ginet, , J. Amer. Chem. Soc., 1999, 141, 10233.

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  11. Chiral phosphinoyl alcohol complexes of monoxobis(peroxo)molybdenum(VI) and their use as asymmetric oxidants, R J Cross, P D Newman, R D Peacock and D Stirling, J Mol Catal, 1999, , 144, 273.

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  12. N,N',N"-1,4,7-triazacyclononane with pendant alkyne arms: Crystal structures of [CuL'2][PF6]2, [NiL'2][ClO4]2 and CuL"Cl2 (L' = N-(4-but-2-yne)-1,4,7-triazacyclononane, L" = N-(5-pent-2-yne)-1,4,7-triazacyclononane), D. Ellis, L.J. Farrugia and R D Peacock, Polyhedron, 1999, 18, 1229.

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  13. Metal Complexes of New Chiral N2O2 Tetradentate Ligands and their Use as Asymmetric Oxidation Catalysts, R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, Inorg Chem, 1999, 38, 1186.

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  14. Stereochemical Synthesis and Crystal Structure of (+)-1S-Benzyl-1-(diphenylphosphoryl)propionic Acid, R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, Phosphorus, Sulphur, Silicon & related elements, 1998, 140, 63.

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  15. Redox reactions between molybdenum or tungsten hexafluorides and p, f or d block elements in acetonitrile. Comparison with reactions involving nitrosonium fluorometallates, the effect of fluoride ligand transfer and redox inhibition due to surface oxide, S I Ajiboye, J Iqbal, R D Peacock, N Prouff, G J Taylor, J M Winfield and X Liu, J Fluorine Chem, 1998, 91, 213.

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  16. Chiral Schiff base complexes of Copper(II), Vanadium(IV) and Nickel(II) as oxidation catalysts. X-ray structures of [Cu(R-salpen)(OH2)] and [Cu(+/-busalcx)], S Bunce, R J Cross, L J Farrugia, S Kunchandy, L L Meason, K W Muir, M O'Donnell, R D Peacock, D Stirling and S Teat, Polyhedron, 1998, 17, 4179.

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  17. Ground and excited state chiroptical properties of enantiopure macrocyclic tetranaphthyl lanthanide complexes: a chiral modulator?, R S Dickins, J A.K. Howard, C L Maupin, J Moloney, D Parker, R D Peacock, J P Reil and G Siligardi, New J of Chem, 1998, 891.

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  18. C-C coupling reactions on a flexible Ru3Pt framework: X-ray crystal structures of Ru3 Pt[(m4-C(But).C(H).C{C(But)}{C(H).C(But)}]{m-s-p-C(H)=C(H)-(But)}(CO)7(dppe), Ru3 Pt[(m3-C(But).C.C(But).CH2](CO)8(dppe) and Ru3Pt{(m4-C(Ph).C.C.C(H)(But)}((m4-Te)((m-TePri)(CO)6(dppe), L J Farrugia and N McDonald and R D Peacock, Polyhedron, 1998, 17, 2877.

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  19. Reversible anion binding in aqueous solution at a cationic heptacoordinate lanthanide centre: selective bicarbonate sensing by time-delayed luminescence, R S Dickens, T Gunnlaugsson, D Parker and R D Peacock, Chem Comm, 1998, 1643.

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  20. X-Ray Circular Dichroism, L Alagna, J Goulon, C Goulon-Ginet, C R Natoli, R D Peacock, T Prosperi, A Rogalev, B Stewart and S Turchini, Phys Rev Letters, 1998, 80, 4799 - 47802.

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  21. Strong Exciton Coupling and Circularly Polarised Luminescence in Rigid Complexes of Chiral Macrocyclic Tetra-naphthylamides, R. S. Dickins, J. A.K. Howard, J. Moloney, R. D. Peacock, D. Parker and G. Siligardi, Chem Comm, 1997, 1747 - 1748.

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  22. Natural Circular Dichroism at the Nd L3 Edge in Single Crystals of Na3Nd(C4H4O5)3 2NaBF4 6H2O, L. Alagna, J. Goulon, C. Goulon-Ginet, R. D. Peacock, T. Prosperi, A. Rogalev, B. Stewart and S. Turchini, J de Physique IV, 1997, 7, Colloque C2, 463-4.

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  23. Halogen Etching of 13-15 semiconductors and its Relevance to Chemomechanical Polishing. The reactions of dibromine, dichlorine and sodium hypochlorite with gallium arsenide and related materials, L McGhee, I Nicol, R D Peacock, M I Robertson, P R Stevenson and J M Winfield, J Mat Chem, 1997, 7, 2421.

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  24. Experimental determination of the electron density topology in a non-centrosymmetric transition metal complex - [Ni(H3L)][NO3][PF6]; H3L = N,N',N''-tris-[(2R)-2-hydroxy-3-methyl-butyl]-1,4,7-triaza cyclononane, L J Farrugia, C R Frampton, J A K Howard, P R Mallinson R D Peacock and G Smith, J Amer Chem Soc, 1997, 119, 5208 - 5234.

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  25. Synthesis of a Series of Novel Binucleating Ligands based on 1,4,7-triazacyclononane and o,m and p-xylene: Crystal Structure of the m-Hydroxy-bridged Di-copper(II) Complex [Cu2Lm(OH)2][BPh4]2 ; Lm = Bis-a,a'-(N-1,4,7-triazacyclononane)-m-xylene, L J Farrugia, P A Lovatt and R D Peacock, Dalton Trans, 1997, 911.

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  26. Structural rigidity and chiral luminescence of lanthanide tetra-amide complexes based on 1,4,7,10-tetraaza- cyclododecane, R S Dickens, J A K Howard, C W Lehmann, J Moloney, D Parker and R D Peacock, Angew Chem Int Ed Engl, 1997,36, 521-522.

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  27. Camphor-based (-hydroxyphosphorylligands and complexes of the type [MoO(O2)(L)(OH)2], R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, J Chem Soc Dalton Trans, 1996, 4149-4150.

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  28. R and S-2-(diphenylphosphinoyl)-2'-hydroxy-1-1'-dinaphthalene: versatile chiral bidentate ligands, R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling J Chem Soc Dalton Trans, 1996, 4449 - 4458.

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  29. Crystal structure and absolute configuration of (1R, 2S, 5R)-menthyl(2S)-2-(diphenyl- phosphinoyl)-propionate: attempted resolution and chiral synthesis of 2-(diphenylphosphinoyl)propionic acid. R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, J Chem Res(S), 1996, 222-223.

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  30. A general route for the synthesis of triazacyclononane functionalised with one, two or three pendant phosphine arms - crystal structure of [Zn2L2Cl3][ClO4], L =N-(diphenylphosphinopropyl)-  1,4,7-triazacyclononane. D Ellis, L J Farrugia, D T Hickman, P A Lovatt and R D Peacock, Chem Comm, 1996, 1817-1818.

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  31. Preparation and Electrochemical Quartz Crystal Microbalance Characterisation of [Os(bipy)2(PVPS)nClRu(edta) Redox Polymers, J A Crayston, D J Cole-Hamilton, A Glidle, C M Lindall and R D Peacock, J Mat Chem, 1996. 1259-1269.

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  32. Structure of the Naphthofuranquinone Dinaphtho[2,1-b.2',3'-d]furan-8-13-dione, C F Scott, L J Farrugia and R D Peacock, Acta Crystallogr C, 1996, C52, 1310-11.

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  33. Macrocycles with a Single Pendant Arm: Synthesis of N-R-(1,4,7-triazacyclononane) (L, R = 4-but-1-ene; L', R = 3-prop-1-ene). Synthesis of the Cu(I) complex [CuL]I and synthesis and crystal structures of the Cu(II) complex [CuL2][BPh4]2 and the µ-hydroxy bridged Cu(II) dimer [LCu(m-OH)2CuL][BPh4]2, L J Farrugia, P A Lovatt and R D Peacock, Inorg Chim. Acta,1996, 246, 343-348.

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  34. Absorption, Circular Dichroism, Luminescence and Infra-red Spectroscopy of Chemically and Electrochemically Reduced Ru(II) and Os(II) Bipyridyl Complexes, B C Noble and R D Peacock, Inorg Chem, 1996, 35, 1616-1620.

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  35. Experimental Determination of the Electron Configuration of the Nickel Ion in a Complexed Macrocycle by X-ray Diffraction I A Fallis, L J Farrugia, C S Frampton, J A K Howard, P Mallinson, R D Peacock and G Smith, Chem Comm, 1996, 525-526.

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  36. Metal Complexes of Chiral Phosphinylalkoxide Ligands: Crystal Structure of Bis[1S-methyl-2-(diphenyl-phosphinyl)ethanolato] dichlorotitanium(IV). R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, J Chem Soc Dalton Trans, 1996, 1637-1643.

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  37. (Diphenylphosphinyl)propanoate complexes: Crystal structure of tris[2-(Diphenylphosphinyl)-propanoato] vanadium(III) R J Cross, L J Farrugia, P D Newman, R D Peacock and D Stirling, J Chem Soc Dalton Trans, 1996, 1087-1092.
  38. Surface Enhanced Resonance Raman Spectroscopy of tris(2,2'-bipyridine) ruthenium(II) and substituted analogues on novel vapour deposited surfaces. M J Edmiston and R D Peacock, Spectrochim. Acta A, 1996, 52A, 191-198.

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  39. Layer Morphology and Growth Mechanism in Barium Ferrites. T Baird, A G Cairns-Smith, G Turner, R D Peacock and B Stewart, J Cryst Growth, 1996, 158, 276-283.

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Some Selected Publications from the PAST

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