Dr. De-Liang Long

Deputy Group Leader
Senior Group Member

Deliang Long is a Senior Research Fellow and the deputy leader of the Cronin group. He has over 30 years research experience in a number of top research institutions, i.e. Wuhan University, Nanjing University, Chinese Academy of Sciences, Nottingham University and Glasgow University. His current role in Glasgow University is to provide scientific leadership, especially in the highly demanding and specialist structural, synthetic and analytical research, to the Cronin group team that allows the group to perform research across such a large number of areas at the cutting edge. He leads research projects ranging from inorganic synthesis to coordination chemistry, optical nonlinearity materials, chemical topology and chemical crystallography. His recent research includes molecular metal oxide (polyoxometalates) synthesis, mass spectrometry, application of chemical crystallography and electron transfer, in connection with which many fundamental new structure types of polyoxometalates have been discovered, for example, the families of {M18O54(XO3)2} and {M18O56(XO6)} (M = Mo or W) with redox active templates XO3 (X = SIV, SeIV and PIII) and XO6 (X = WVI, TeVI and IVII) etc. He organises and runs the x-ray crystallography work which takes great challenges in resolving molecular and supramolecular structures of protein-sized inorganic clusters such as Molybdeum Blue {Mo186} and polyoxotungstate {W200}. He has published over 230 papers which have been cited about 10,000 times (H index = 51) including papers on top journals Science, Nature and Nature group, Angew. Chem., and JACS. He has given over 40 invited lectures in international conferences, universities and research institutes, leads a number of international collaborations, and was a guest-editor on a special issue of Dalton in 2012.

Member Publications

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Open Access

200. Elucidating the Paramagnetic Interactions of an Inorganic-Organic Hybrid Radical-Functionalized Mn-Anderson Cluster, L. Cronin, C. -G. Lin, M. Hutin, C. Busche, N. L. Bell, D. -L. Long, Dalton Trans., 2021, 50, 2350-2353.

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Open Access

199. Peptide sequence mediated self-assembly of molybdenum blue nanowheel superstructures, S. She, W. Xuan, N. Bell, R. Pow, E. Garrido Ribo, Z. Sinclair, D. -L. Long, L. Cronin, Chem. Sci., 2021, 12, 2427-2432.

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198. Synthesis, Assembly, and Sizing of Neutral, Lanthanide Substituted Molybdenum Blue Wheels {Mo90Ln10}, E. Garrido Ribo, N. Bell, W. Xuan, J. Luo, D. -L. Long, T. Liu, L. Cronin, J. Am. Chem. Soc., 2020, 142, 17508-17514.

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Open Access

197. A Modular Programmable Inorganic Cluster Discovery Robot for the Discovery and Synthesis of Polyoxometalates, D. Salley, G. Keenan, D. -L. Long, N. Bell, L. Cronin, ACS Cent. Sci, 2020, 6, 1587-1593.

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196. Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters, H. N. Miras, C. Mathis, W. Xuan, D. -L. Long, R. Pow, L. Cronin, Proc. Natl. Acad. Sci. USA, 2020, 117, 10699-10705.

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Open Access

195. An autonomous chemical robot discovers the rules of supramolecular chemistry without prior knowledge, L. Porwol, D. Kowalski, A. Henson, D. -L. Long, N. L. Bell, L. Cronin, Angew. Chem. Int. Ed., 2020, 59, 11256-11261.

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Open Access

194. Embedding alkenes within an icosahedral inorganic fullerene {(NH4)42[Mo132O372(L)30(H2O)72]} for trapping volatile organics, R. Pow, W. Xuan, D. -L. Long, N. Bell, L. Cronin, Chem. Sci., 2020, 11, 2388-2393.

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Open Access

193. Controlling the Reactivity of the [P8W48O184]40− Inorganic Ring and Its Assembly into POMZite Inorganic Frameworks with Silver Ions, C. Zhan, Q. Zheng, D. -L. Long, L. Vilà-Nadal, L. Cronin, Angew. Chem. Int. Ed., 2019, 131, 17442-17446.

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Open Access

Preprint 4. Spontaneous Formation of Autocatalytic Sets with Self-Replicating Inorganic Metal Oxide Clusters, H. N. Miras, C. Mathis, W. Xuan, D.-L. Long, R. Pow, L. Cronin, ChemRxiv, 2019.

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Open Access

192. Ligand-Directed Template Assembly for the Construction of Gigantic Molybdenum Blue Wheels, W. Xuan, R. Pow, Q. Zheng, N. Watfa, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2019, 58, 10867-10872.

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Open Access

191. Anisotropic polyoxometalate cages assembled via layers of heteroanion templates, Q. Zheng, M. Kupper, W. Xuan, H. Oki, R. Tsunashima, D. -L. Long, L. Cronin, J. Am. Chem. Soc., 2019, 141, 13479-13486.

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Open Access

Preprint 3. Enantioselective Recognition of Chiral Guests by the Water-Soluble Chiral [Mo132O372(H2O)72(x-Lactate)30]42- Nanocapsules, N. Watfa, W. Xuan, Z. Sinclair, R. Pow, Y. M. Abul-Haija, D. -L. Long, L. Cronin, ChemRxiv, 2019.

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Open Access

190. Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection†, E. Janusson, N. de Kler, L. Vilà-Nadal, D. -L. Long, L. Cronin, Chem. Commun., 2019, 55, 5797-5800.

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Open Access

189. Stereoselective Assembly of Gigantic Chiral Molybdenum Blue Wheels Using Lanthanide ions and Amino Acids, W. Xuan, R. Pow, N. Watfa, Q. Zheng, A. J. Surman, D. -L. Long, L. Cronin, J. Am. Chem. Soc., 2019, 141, 1242-1250.

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Open Access

Preprint 2. Pyramidal Heteroanion-Directed and Reduced MoV-Driven Assembly of Multi-Layered Polyoxometalate Cages, Q. Zheng, M. Kupper, H. Oki, R. Tsunashima, D. -L. Long, L. Cronin, ChemRxiv, 2018.

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Open Access

Preprint 1. Unveiling the Key Templates in the Self-Assembly of Gigantic Molybdenum Blue Wheels, W. Xuan, R. Pow, Q. Zheng, N. Watfa, D. -L. Long, L. Cronin, ChemRxiv, 2018.

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Open Access

188. Digital Control of Multistep Hydrothermal Synthesis by Using 3D Printed Reactionware for the Synthesis of Metal-Organic Frameworks., C. -G. Lin, W. Bains, X. -T. Xiong, W. Xuan, P. J. Kitson, D. -L. Long, W. Chen, Y. -F. Song, L. Cronin, Angew. Chem. Int. Ed., 2018, 57, 16716-16720.

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187. Controlling an organic synthesis robot with machine learning to search for new reactivity, J. Granda, L Donina, V. Dragone, D. -L. Long, L. Cronin, Nature, 2018, 559, 377-381.

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Open Access

186. Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates, J. W. Purcell, D. -L. Long, E. Lee, L. Cronin, H. N. Miras, Dalton Trans., 2018, 47, 6283-6287.

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185. Directed Self-Assembly, Symmetry Breaking, and Electronic Modulation of Metal Oxide Clusters by Pyramidal Heteroanions, C. Sartzi, D. -L. Long, S. Sproules, L. Cronin, H. N. Miras, Chem. Eur. J., 2018, 24, 4399-4411.

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Open Access

184. Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction, M. M. Sabi, J. Soriano-Lopez, R. S. Winter, J. -J. Chen, L. Vilà-Nadal, D. -L. Long, J. R. Galan-Mascaros, L. Cronin, Nat. Cat., 2018, 1, 208-213.

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183. Design and Performance of Rechargeable Sodium Ion Batteries, and Symmetrical Li-Ion Batteries with Supercapacitor-Like Power Density Based upon Polyoxovanadates, J. -J. Chen, J. -C. Ye, X. -G. Zhang, M. D. Symes, S. -C. Fan, D. -L. Long, M. -S. Zheng, D. -Y. Wu, L. Cronin, Q. -F. Dong, Adv. Energy Mater., 2018, 8, 1701021.

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182. Self-Sorting of Heteroanions in the Assembly of Cross-Shaped Polyoxometalate Clusters, Q. Zheng, L. Vilà-Nadal, Z. Lang, J. -J. Chen, D. -L. Long, J. S. Mathieson, J. M. Poblet, L. Cronin, J. Am. Chem. Soc., 2018, 140, 2595-2601.

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Open Access

181. Human vs Robots in the discovery and crystallization of gigantic polyoxometalates, V. Duros, J. Grizou, W. Xuan, Z. Hosni, D. -L. Long, H. N. Miras, L. Cronin, Angew. Chem. Int. Ed., 2017, 56, 10815-10820.

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Open Access

180. Exploring the Molecular Growth of Two Gigantic Half-Closed Polyoxometalate Clusters {Mo180} and {Mo130Ce6}, W. Xuan, R. Pow, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2017, 56, 9727–9731.

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Open Access

179. Tellurite-squarate driven sssembly of a new family of nanoscale clusters based on (Mo2O2S2)2+, J. W. Purcell, H. N. Miras, D. -L. Long, P. Markopoulou, L. Cronin, Chem. Eur. J., 2017, 23, 9683-9689.

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Open Access

178. Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}, H. -Y. Zang, J. W. Purcell, D. -L. Long, H. N. Miras, L. Cronin, Chem. Commun., 2017, 53, 8585-8587.

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Open Access

177. Encapsulation of a {Cu16} cluster containing four [Cu4O4] cubanes within an isopolyoxometalate {W44} cluster, C. Zhan, C. Busche, D. -L. Long, P. I. Molina, R. S. Winter, L. Cronin, Chem. Commun., 2017, 53, 7076-7079.

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Open Access

176. Coding the assembly of polyoxotungstates with a programmable reaction system, A. R. de la Oliva, V. Sans, H. N. Miras, D. -L. Long, L. Cronin, Inorg. Chem., 2017, 56, 5089-5095.

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Open Access

175. POMzites: A Family of zeolitic polyoxometalate frameworks from a minimal building block library, T. Boyd, S. G. Mitchell, D. Gabb, D. -L. Long, Y. -F. Song, L. Cronin, J. Am. Chem. Soc., 2017, 139, 5930-5938.

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Open Access

174. A metamorphic inorganic framework that can be switched between eight single-crystalline states, C. Zhan, J. M. Cameron, D. Gabb, T. Boyd, R. S. Winter, L. Vilà-Nadal, S. G. Mitchell, S. Glatzel, J. Breternitz, D. H. Gregory, D. -L. Long, A. Macdonell, L. Cronin, Nat. Commun., 2017, 8, 14185.

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173. Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters, H. N. Miras, D. -L. Long, L. Cronin, Adv. Inorg. Chem., 2017, 69, 1-28.

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Open Access

172. Spontaneous Assembly of an Organic–Inorganic Nucleic Acid Z-DNA Double-Helix Structure, V. Kulikov, N. A. B. Johnson, A. J. Surman, M. Hutin, S. M. Kelly, M. Hezwani, D. -L. Long, G. Meyer, L. Cronin, Angew. Chem. Int. Ed., 2017, 56, 1141-1145.

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Open Access

171. Overcoming the Crystallization Bottleneck: A Family of Gigantic Inorganic {Pdx}L (x=84, 72) Palladium Macrocycles Discovered using Solution Techniques, L. G. Christie, A. J. Surman, R. A. Scullion, F. Xu, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2016, 55, 12741-12745.

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Open Access

170. Self-Templating and In Situ Assembly of a Cubic Cluster-of-Clusters Architecture Based on a {Mo24Fe12} Inorganic Macrocycle, W. Xuan, A. J. Surman, Q. Zheng, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2016, 55, 12703-12707.

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Open Access

169. Water-Soluble Pentagonal-Prismatic Titanium-Oxo Clusters, G. Zhang, C. Liu, D. -L. Long, L. Cronin, C. Tung, Y. Wang, J. Am. Chem. Soc., 2016, 138, 11097-11100.

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168. On the fly multi-modal observation of ligand synthesis and complexation of Cu complexes in flow with ‘benchtop’ NMR and mass spectrometry, L. Porwol, A. Henson, P. J. Kitson, D. -L. Long, L. Cronin, Inorg. Chem. Front., 2016, 3, 919-923.

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Open Access

167. Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks, H. -Y. Zang, A. J. Surman, D. -L. Long, L. Cronin, H. N. Miras, Chem. Commun., 2016, 52, 9109-9912.

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Open Access

166. Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide-polyoxometalate clusters, H. -Y. Zang, J. -J. Chen, D. -L. Long, L. Cronin, H. N. Miras, Chem. Sci., 2016, 7, 3798-3804.

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165. Trapping the δ Isomer of the Polyoxometalate-Based Keggin Cluster with a Tripodal Ligand, C. Sartzi, H. N. Miras, L. Vilà-Nadal, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2015, 54, 15488-15492.

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164. Electronically Stabilized Nonplanar Phenalenyl Radical and Its Planar Isomer, O. Anamimoghadam, M. D. Symes, D. -L. Long, S. Sproules, L. Cronin, G. Bucher, J. Am. Chem. Soc., 2015, 137, 14944-14951.

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163. Assembly of Tungsten-Oxide-Based Pentagonal Motifs in Solution Leads to Nanoscale {W48}, {W56}, and {W92} Polyoxometalate Clusters, C. Zhan, R. S. Winter, Q. Zheng, J. Yan, J. M. Cameron, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2015, 54, 14308-14312.

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Open Access

162. Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters, M. M. Sabi, R. S. Winter, C. Lydon, J. M. Cameron, D. -L. Long, L. Cronin, Chem. Commun., 2016, 52, 919-921.

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Open Access

161. Following the Reaction of Heteroanions inside a {W18O56} Polyoxometalate Nanocage by NMR Spectroscopy and Mass Spectrometry, Q. Zheng, L. Vilà-Nadal, C. Busche, J. S. Mathieson, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2015, 54, 7895-7899.

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160. Synthesis and Characterization of a Series of [M2(β-SiW8O31)2]n− Clusters and Mechanistic Insight into the Reorganization of {β-SiW8O31} into {α-SiW9O34}, R. S. Winter, D. -L. Long, L. Cronin, Inorg. Chem., 2015, 54, 4151-4155.

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159. The Effect of the Spacer of Bis(biurea) Ligands on the Structure of A2L3-type (A=anion) Phosphate Complexes, B. Wu, S. Li, Y. Lei, H. Hu, N. de Sousa Amadeu, C. Janiak, J. S. Mathieson, D. -L. Long, L. Cronin, X.-J. Yang, Chem. Eur. J., 2015, 21, 2588-2593.

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158. Design and fabrication of memory devices based on nanoscale polyoxometalate clusters, C. Busche, L. Vilà-Nadal, J. Yan, H. N. Miras, D. -L. Long, V. P. Georgiev, A. Asenov, R. H. Pedersen, N. Gadegaard, M. M. Mirza, D. J. Paul, J. M. Poblet, L. Cronin, Nature, 2014, 515, 545-549.

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157. 3D Printed High-Throughput Hydrothermal Reactionware for Discovery, Optimization, and Scale-Up, P. J. Kitson, R. J. Marshall, D. -L. Long, R. S. Forgan, L. Cronin, Angew. Chem. Int. Ed., 2014, 53, 12723-12728.

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156. Controlling the Ring Curvature, Solution Assembly, and Reactivity of Gigantic Molybdenum Blue Wheels, W. Xuan, A. J. Surman, H. N. Miras, D. -L. Long, L. Cronin, J. Am. Chem. Soc., 2014, 136, 14114-14120.

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155. Time-Resolved Assembly of Cluster-in-Cluster {Ag12}-in-{W76} Polyoxometalates under Supramolecular Control, C. Zhan, J. M. Cameron, J. Gao, J. W. Purcell, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2014, 53, 10362-10366.

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Prof. Leroy (Lee) Cronin

Prof Leroy (Lee) Cronin
Regius Chair of Chemistry
Advanced Research Centre (ARC)
Level 5, Digital Chemistry
University of Glasgow
11 Chapel Lane
Glasgow G11 6EW
Tel: +44 141 330 6650
Email: lee.cronin@glasgow.ac.uk

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