Dr. Haralampos Miras

Senior Lecturer
Senior Group Member

Haralampos N. Miras was born in Athens, Greece. He gained his BSc degree in chemistry from Ioannina University and obtained his PhD under the supervision of Prof. T. A. Kabanos at Ioannina University in 2004. In 2005 he moved to the University of Rio Piedras, Puerto Rico, USA to take up a post-doctoral fellowship with Prof. R. G. Raptis in pyrazolate based coordination materials. In 2006 he was offered a research associate position by Prof. Cronin at the University of Glasgow in the area of discovery, synthesis and mechanistic studies using ESI/CSI-MS of large polyoxometalate and coordination clusters. In 2010 was awarded a Royal Society of Edinburgh (RSE) research fellow co-funded by Marie Curie actions. He is currently leader of the complex chemical systems sub-group, within the Cronin group. His research interests are focusing in polyoxometalate, chalcogenide and coordination chemistry.

Research interests: My research interests are primarily focused on the investigation and development of metal oxide/chalcogenide based surfaces for energy applications (H2 production, water oxidation, catalytic processes etc.). The current research is dedicated to the discovery of simple preparation routes to mesoporous polyoxometalate-based composite materials for oxidative catalysis and understanding of fundamental processes in the self-assembly of supramolecular coordination compounds with modular magnetic properties as well as the investigation of their electronic structure, electrochemical behaviour and electrocatalytic activity. A synergistic research strand which is being developed in parallel in collaboration with Prof. Leroy Cronin, involves the fundamental understanding, control and design of self-assembled complex chemical systems. I am interested in exploiting novel methodologies (continuous flow processing and microfluidics) for the discovery and design of functional molecular devices. Other recent research projects have investigated the discovery of intermediate reaction structures in an effort to understand the underlying chemistry in the self-assembly of polyoxometalate systems and extraction of crucial mechanistic information utilizing high resolution ESI-MS techniques.

Member Publications

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67. Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters, H. N. Miras, C. Mathis, W. Xuan, D. -L. Long, R. Pow, L. Cronin, Proc. Natl. Acad. Sci. USA, 2020, 117, 10699-10705.

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Open Access

Preprint 1. Spontaneous Formation of Autocatalytic Sets with Self-Replicating Inorganic Metal Oxide Clusters, H. N. Miras, C. Mathis, W. Xuan, D.-L. Long, R. Pow, L. Cronin, ChemRxiv, 2019.

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Open Access

66. Intuition-enabled Machine Learning beats the Competition when Joint Human-Robot Teams per-form Inorganic Chemical Experiments, V. Duros, J. Grizou, A. Sharma, S. Hessam M. Mehr, A. Bubliauskas, P. Frei, H. N. Miras, L. Cronin, J. Chem. Inf. Model, 2019, 59, 2664-2671.

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65. Integrated synthesis of gold nanoparticles coated with polyoxometalate clusters, S. Martin, Y. Takashima, C. -G. Lin, Y. -F. Song, H. N. Miras, L. Cronin, Inorg. Chem., 2019, 58, 4110-4116.

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Open Access

64. Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates, J. W. Purcell, D. -L. Long, E. Lee, L. Cronin, H. N. Miras, Dalton Trans., 2018, 47, 6283-6287.

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63. Directed Self-Assembly, Symmetry Breaking, and Electronic Modulation of Metal Oxide Clusters by Pyramidal Heteroanions, C. Sartzi, D. -L. Long, S. Sproules, L. Cronin, H. N. Miras, Chem. Eur. J., 2018, 24, 4399-4411.

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Open Access

62. Human vs Robots in the discovery and crystallization of gigantic polyoxometalates, V. Duros, J. Grizou, W. Xuan, Z. Hosni, D. -L. Long, H. N. Miras, L. Cronin, Angew. Chem. Int. Ed., 2017, 56, 10815-10820.

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Open Access

61. Tellurite-squarate driven sssembly of a new family of nanoscale clusters based on (Mo2O2S2)2+, J. W. Purcell, H. N. Miras, D. -L. Long, P. Markopoulou, L. Cronin, Chem. Eur. J., 2017, 23, 9683-9689.

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Open Access

60. Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}, H. -Y. Zang, J. W. Purcell, D. -L. Long, H. N. Miras, L. Cronin, Chem. Commun., 2017, 53, 8585-8587.

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Open Access

59. Coding the assembly of polyoxotungstates with a programmable reaction system, A. R. de la Oliva, V. Sans, H. N. Miras, D. -L. Long, L. Cronin, Inorg. Chem., 2017, 56, 5089-5095.

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58. Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters, H. N. Miras, D. -L. Long, L. Cronin, Adv. Inorg. Chem., 2017, 69, 1-28.

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57. Shrink wrapping redox-active crystals of polyoxometalate open frameworks with organic polymers via crystal induced polymerisation, Y. Takashima, H. N. Miras, S. Glatzel, L. Cronin, Chem. Commun., 2016, 52, 7794-7797.

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Open Access

56. Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks, H. -Y. Zang, A. J. Surman, D. -L. Long, L. Cronin, H. N. Miras, Chem. Commun., 2016, 52, 9109-9912.

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Open Access

55. Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide-polyoxometalate clusters, H. -Y. Zang, J. -J. Chen, D. -L. Long, L. Cronin, H. N. Miras, Chem. Sci., 2016, 7, 3798-3804.

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54. Trapping the δ Isomer of the Polyoxometalate-Based Keggin Cluster with a Tripodal Ligand, C. Sartzi, H. N. Miras, L. Vilà-Nadal, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2015, 54, 15488-15492.

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53. High-Performance Polyoxometalate-Based Cathode Materials for Rechargeable Lithium-Ion Batteries, J. -J. Chen, M. D. Symes, S. -C. Fan, M. -S. Zheng, H. N. Miras, Q. -F. Dong, L. Cronin, Adv. Mater., 2015, 27, 4649-4654.

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Open Access

52. Investigating the Formation of Molybdenum Blues with Gel Electrophoresis and Mass Spectrometry, I. Nakamura, H. N. Miras, A. Fujiwara, M. Fujibayashi, Y.-F. Song, L. Cronin, R. Tsunashima, J. Am. Chem. Soc., 2015, 137, 6524-6530.

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51. Design and fabrication of memory devices based on nanoscale polyoxometalate clusters, C. Busche, L. Vilà-Nadal, J. Yan, H. N. Miras, D. -L. Long, V. P. Georgiev, A. Asenov, R. H. Pedersen, N. Gadegaard, M. M. Mirza, D. J. Paul, J. M. Poblet, L. Cronin, Nature, 2014, 515, 545-549.

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50. Controlling the Ring Curvature, Solution Assembly, and Reactivity of Gigantic Molybdenum Blue Wheels, W. Xuan, A. J. Surman, H. N. Miras, D. -L. Long, L. Cronin, J. Am. Chem. Soc., 2014, 136, 14114-14120.

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49. Polyoxometalate based open-frameworks (POM-OFs), H. N. Miras, L. Vilà-Nadal, L. Cronin, Chem. Soc. Rev., 2014, 43, 5679-5699.

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Open Access

48. Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine, H. -Y. Zang, A. R. de la Oliva, H. N. Miras, D. -L. Long, R. T. McBurney, L. Cronin, Nat. Commun., 2014, 5, 3715.

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47. Assembly and core transformation properties of two tetrahedral clusters: [FeIII13P8W60O227(OH)15(H2O)2]30- and [FeIII13P8W60O224(OH)12(PO4)4]33-, P. I. Molina, H. N. Miras, D. -L. Long, L. Cronin, Dalton Trans., 2014, 43, 5190-5199.

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46. A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage, D. -L. Long, J. Yan, A. R. de la Oliva, C. Busche, H. N. Miras, J. R. Errington, L. Cronin, Chem. Commun., 2013, 49, 9731-9733.

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45. Assembly of thiometalate-based {Mo16} and {mo36} composite clusters combining [Mo2O2S2]2+ cations and selenite anions, H. -Y. Zang, J. -J. Chen, D. -L. Long, L. Cronin, H. N. Miras, Adv. Mater., 2013, 25, 6245-6249.

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44. Exploring the Assembly of Supramolecular Polyoxometalate Triangular Morphologies with Johnson Solid Cores: [(MnII(H2O)3)2(K ⊂ {α-GeW10MnII2O38}3)]19-, P. I. Molina, H. N. Miras, D. -L. Long, L. Cronin, Inorg. Chem., 2013, 52, 9284-9289.

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43. Template-Directed Assembly of Polyoxothiometalate Scaffolds into Nanomolecular Architectures, H. -Y. Zang, H. N. Miras, D. -L. Long, B. Rausch, L. Cronin, Angew. Chem. Int. Ed., 2013, 52, 6903-6906.

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42. Assembly of a Gigantic Polyoxometalate Cluster {W200Co8O660} in a Networked Reactor System, A. R. de la Oliva, V. Sans, H. N. Miras, J. Yan, H. Zang, C. J. Richmond, D. -L. Long, L. Cronin, Angew. Chem. Int. Ed., 2012, 51, 12759-12762.

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41. Sulfite Anions as Structure-Directing Templates for the Engineering of Modular Polyoxometalates, H. N. Miras, G. I. Chilas, L. Cronin, T. -K. Ng, Eur. J. Inorg. Chem., 2013, 0, 1620-1630.

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40. A flow-system array for the discovery and scale up of inorganic clusters, C. J. Richmond, H. N. Miras, A. R. de la Oliva, H. Zang, V. Sans, L. Paramonov, C. Makatsoris, R. Inglis, E. K. Brechin, D. -L. Long, L. Cronin, Nature Chem., 2012, 4, 1037-1043.

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39. Controlling the Self-Assembly of a Mixed-Metal Mo/VSelenite Family of Polyoxometalates, M. N. C. Ochoa, H. N. Miras, D. -L. Long, L. Cronin, Chem. Eur. J., 2012, 18, 13743-13754.

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38. Engineering polyoxometalates with emergent properties, H. N. Miras, J. Yan, D. -L. Long, L. Cronin, Chem. Soc. Rev., 2012, 41, 7403-7430.

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37. Correlating the magic numbers of inorganic nanomolecular assemblies with a {Pd84} molecular-ring Rosetta Stone, F. Xu, H. N. Miras, R. Scullion, D. -L. Long, J. Thiel, L. Cronin, Proc. Natl. Acad. Sci. USA, 2012, 109, 11609-11612.

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36. Organic-soluble lacunary {M2(P2W15)2} polyoxometalate sandwiches showing a previously unseen αββα isomerism., D. Gabb, C. P. Pradeep, H. N. Miras, S. Mitchell, D. -L. Long, L. Cronin, Dalton Trans., 2012, 41, 10000-10005.

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35. Assembly and Autochirogenesis of a Chiral Inorganic Polythioanion Mobius Strip via Symmetry Breaking, H. Zang, H. N. Miras, J. Yan, D. -L. Long, L. Cronin, J. Am. Chem. Soc., 2012, 134, 11376-11379.

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34. Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv), F. Li, D. -L. Long, J. M. Cameron, H. N. Miras, C. P. Pradeep, L. Xu, L. Cronin, Dalton Trans., 2012, 41, 9859-9862.

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33. Oscillatory Template Exchange in Polyoxometalate Capsules: A Ligand-Triggered, Redox-Powered, Chemically Damped Oscillation, H. N. Miras, M. Sorus, J. Hawkett, D. O. Sells, E. J. L. McInnes, L. Cronin, J. Am. Chem. Soc., 2012, 134, 6980-6983.

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32. Nanoscale Growth of Molecular Oxides: Assembly of a {V6} Double Cubane Between Two Lacunary {P2W15} Polyoxometalates, C. Lydon, C. Busche, H. N. Miras, A. Delf, D. -L. Long, L. Yellowlees, L. Cronin, Angew. Chem. Int. Ed., 2012, 51, 2115-2118.

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31. Solution-Phase Monitoring of the Structural Evolution of a Molybdenum Blue Nanoring, H. N. Miras, C. J. Richmond, D. -L. Long, L. Cronin, J. Am. Chem. Soc., 2012, 134, 3816-3824.

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30. Direct Synthesis and Mass Spectroscopic Observation of the {M40} Polyoxothiometalate Wheel, H. N. Miras, H. Zang, D. -L. Long, L. Cronin, Eur. J. Inorg. Chem., 2011, 33, 5105-5111.

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29. A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands, S. G. Mitchell, P. I. Molina, S. Khanra, H. N. Miras, A. Prescimone, G. J. T. Cooper, R. S. Winter, E. K. Brechin, D. -L. Long, R. Cogdell, L. Cronin, Angew. Chem. Int. Ed., 2011, 50, 9154-9157.

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28. Connecting Theory with Experiment to Understand the Initial Nucleation Steps of Heteropolyoxometalate Clusters, L. Vilà-Nadal, S. G. Mitchell, A. Rodríguez-Fortea, H. N. Miras, L. Cronin, J. M. Poblet, Phys. Chem. Chem. Phys., 2011, 13, 20136-20145.

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27. Exploring the Structure and Properties of Transition Metal Templated {VM(17)(VO(4))(2)} Dawson-Like Capsules, H. N. Miras, D. Stone, D. -L. Long, E. J. L. McInnes, P. Kögerler, L. Cronin, Inorg. Chem., 2011, 50, 8384-8391.

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26. Combined Theoretical and Mass Spectrometry Study of the Formation-Fragmentation of Small Polyoxomolybdates, L. Vilà-Nadal, E. F. Wilson, H. N. Miras, A. Rodríguez-Fortea, L. Cronin, J. M. Poblet, Inorg. Chem., 2011, 50, 7811-7819.

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25. Assembly of a family of mixed metal {Mo : V} polyoxometalates templated by TeO32−: {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}, M. N. C. Ochoa, H. N. Miras, A. Kidd, D. -L. Long, L. Cronin, Chem. Commun., 2011, 47, 8799-8801.

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24. Design and Synthesis of Dumb-bell and Triangular InorganicOrganic Hybrid Nanopolyoxometalate Clusters and Their Characterisation through ESI-MS Analyses, C. P. Pradeep, F.-Y. Li, C. Lydon, H. N. Miras, D. -L. Long, L. Xu, L. Cronin, Chem. Eur. J., 2011, 17, 7472-7479.

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23. Self-assembly of a family of macrocyclic polyoxotungstates with emergent material properties, J. Gao, J. Yan, S. G. Mitchell, H. N. Miras, A. G. Boulay, D. -L. Long, L. Cronin, Chem. Sci., 2011, 2, 1502-1508.

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22. Real-Time Observation of the Self-Assembly of Hybrid Polyoxometalates Using Mass Spectrometry, E. F. Wilson, H. N. Miras, M. H. Rosnes, L. Cronin, Angew. Chem. Int. Ed., 2011, 50, 3720-3724.

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21. A Supramolecular Heteropolyoxopalladate {Pd15} Cluster Host Encapsulating a {Pd2} Dinuclear Guest: [PdII2{H7PdII15O10(PO4)10}]9−, F. Xu, R. A. Scullion, J. Yan, H. N. Miras, C. Busche, A. Scandurra, B. Pignataro, D. -L. Long, L. Cronin, J. Am. Chem. Soc., 2011, 133, 4684-4686.

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20. Programmable Surface Architectures Derived from Hybrid Polyoxometalate-Based Clusters, C. Musumeci, A. Luzio, C. P. Pradeep, H. N. Miras, M. H. Rosnes, Y. -F. Song, D. -L. Long, L. Cronin, B. Pignataro, J. Phys. Chem. C, 2011, 115, 4446-4455.

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19. A dimeric polyoxometalate sandwich motif containing a truncated {Mn3O4} cubane core, S. G. Mitchell, H. N. Miras, D. -L. Long, L. Cronin, Inorg. Chim. Acta, 2010, 363, 4240-4246.

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Prof. Leroy (Lee) Cronin

Prof Leroy (Lee) Cronin
Regius Chair of Chemistry
Advanced Research Centre (ARC)
Level 5, Digital Chemistry
University of Glasgow
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