 
#  CIF produced by WinGX routine CIF_UPDATE
#  Created on 2000-04-10 at 12:20:27
#  Using CIFtbx version 2.6.2 16 Jun 1998
 
#  Dictionary name : cif_core.dic
#  Dictionary vers : 2.1
#  Request file    : c:\wingx\files\archive.dat
#  CIF files read  : ljf006 dreduc struct datcol difabs
 
 
data_ljf006
 
_audit_creation_date            2000-04-10T12:20:27-00:00
_audit_creation_method         'WinGX routine CIF_UPDATE'
_audit_conform_dict_name        cif_core.dic
_audit_conform_dict_version     2.1
_audit_conform_dict_location    ftp://ftp.iucr.org/pub/cif_core.dic
_publ_requested_category        FM
 
#----------------------------------------------------------------------------#
#                   CHEMICAL INFORMATION                                     #
#----------------------------------------------------------------------------#
 
_chemical_name_systematic
;
 ?
;
_chemical_formula_moiety                'C76 H68 Cl4 O4 P4 Pt2'
_chemical_formula_structural            'C76 H68 Cl4 O4 P4 Pt2'
_chemical_formula_sum                   'C76 H68 Cl4 O4 P4 Pt2'
_chemical_formula_weight                1701.16
_chemical_compound_source               'synthesis as described'
 
#----------------------------------------------------------------------------#
#                   UNIT CELL INFORMATION                                    #
#----------------------------------------------------------------------------#
 
_symmetry_cell_setting                  triclinic
_symmetry_space_group_name_H-M          'P -1'
_symmetry_space_group_name_Hall         '-P 1'
_symmetry_Int_Tables_number             2
loop_
    _symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
 
_cell_length_a                          9.9438(9)
_cell_length_b                          14.7383(13)
_cell_length_c                          15.132(2)
_cell_angle_alpha                       71.990(11)
_cell_angle_beta                        89.553(9)
_cell_angle_gamma                       83.186(7)
_cell_volume                            2093.1(4)
_cell_formula_units_Z                   1
_cell_measurement_temperature           291(2)
_cell_measurement_reflns_used           25
_cell_measurement_theta_min             18.23
_cell_measurement_theta_max             20.07
_cell_measurement_wavelength            0.71073
loop_
    _cell_measurement_refln_index_h
    _cell_measurement_refln_index_k
    _cell_measurement_refln_index_l
    _cell_measurement_refln_theta
8 -2 -5 18.23
2 13 3 18.41
9 -2 -4 19.9
7 -3 -8 18.46
5 11 0 18.3
-1 -13 -4 18.23
8 -5 -4 19.19
4 12 7 18.63
3 13 7 19.2
3 -8 6 18.46
6 -8 -9 20.01
1 13 4 18.23
6 10 0 18.25
9 3 -2 19.2
7 -1 -8 18.26
5 -1 -11 18.48
5 11 7 18.46
1 -13 -6 18.93
8 -4 4 20.07
7 9 3 18.23
2 -9 6 18.96
8 3 6 18.48
-1 13 6 18.92
8 -3 -7 19.59
-1 -11 -11 18.86
 
 
#----------------------------------------------------------------------------#
#                   CRYSTAL INFORMATION                                      #
#----------------------------------------------------------------------------#
 
_exptl_crystal_description              plate
_exptl_crystal_colour                   'pale yellow'
_exptl_crystal_size_max                 0.35
_exptl_crystal_size_mid                 0.25
_exptl_crystal_size_min                 0.1
_exptl_crystal_density_diffrn           1.35
_exptl_crystal_density_method           'not measured'
_exptl_crystal_F_000                    840
_exptl_special_details
;
 ?
;
 
#----------------------------------------------------------------------------#
#                   ABSORPTION CORRECTION                                    #
#----------------------------------------------------------------------------#
 
_exptl_absorpt_coefficient_mu           3.583
_exptl_absorpt_factor_muR               0.538
_exptl_absorpt_correction_type          refdelf
_exptl_absorpt_process_details
;
        Walker, N. & Stuart, D (1983) Acta. Cryst. A39, 158-166
;
_exptl_absorpt_correction_T_min         0.2608
_exptl_absorpt_correction_T_max         0.5842
 
#----------------------------------------------------------------------------#
#                   DATA COLLECTION                                          #
#----------------------------------------------------------------------------#
 
_diffrn_source                          'Enraf Nonius FR590'
_diffrn_ambient_temperature             291(2)
_diffrn_radiation_wavelength            0.71073
_diffrn_radiation_type                  MoK\a
_diffrn_radiation_monochromator         graphite
_diffrn_radiation_probe                 x-ray
_diffrn_detector                        'scintillation LiI'
_diffrn_detector_dtime                  1.195
loop_
    _diffrn_attenuator_code
    _diffrn_attenuator_scale
0 0
 
_diffrn_orient_matrix_type
;
  x-axis points to radiation source
  the matrix is specified in reciprocal space
;
_diffrn_orient_matrix_ub_11             0.33729E-1
_diffrn_orient_matrix_ub_12             -0.42971E-1
_diffrn_orient_matrix_ub_13             -0.37132E-1
_diffrn_orient_matrix_ub_21             -0.23786E-1
_diffrn_orient_matrix_ub_22             0.53903E-1
_diffrn_orient_matrix_ub_23             -0.58614E-1
_diffrn_orient_matrix_ub_31             0.92584E-1
_diffrn_orient_matrix_ub_32             0.19987E-1
_diffrn_orient_matrix_ub_33             0.00081
loop_
    _diffrn_orient_refln_angle_chi
    _diffrn_orient_refln_angle_kappa
    _diffrn_orient_refln_angle_phi
    _diffrn_orient_refln_angle_psi
    _diffrn_orient_refln_index_h
    _diffrn_orient_refln_index_k
    _diffrn_orient_refln_index_l
52.071 69.895 -114.713 0.049 8 -2 -5
30.143 39.674 38.565 0.003 2 13 3
55.328 74.589 -125.294 0.053 9 -2 -4
40.586 53.824 -96.059 0.003 7 -3 -8
50.418 67.538 9.44 -0.017 5 11 0
-23.772 -31.185 -113.145 0.015 -1 -13 -4
43.427 57.74 -129.087 0.031 8 -5 -4
43.131 57.331 58.15 0.028 4 12 7
35.823 47.327 57.251 0.026 3 13 7
7.937 10.364 -168.758 -0.002 3 -8 6
23.718 31.113 -103.169 0.011 6 -8 -9
23.759 31.167 46.495 0.014 1 13 4
58.785 79.659 1.649 0.012 6 10 0
73.874 103.303 -114.329 -0.043 9 3 -2
44.639 59.421 -86.78 -0.005 7 -1 -8
29.031 38.186 -65.257 -0.003 5 -1 -11
50.426 67.549 60.23 0.061 5 11 7
-10.854 -14.18 -110.044 -0.003 1 -13 -6
43.295 57.558 -174.903 0.071 8 -4 4
70.19 97.236 25.265 0.07 7 9 3
0.663 0.865 -165.629 0 2 -9 6
64.206 87.824 136 0.147 8 3 6
10.839 14.161 60.812 0.008 -1 13 6
45.521 60.649 -105.527 0.024 8 -3 -7
-20.646 -27.049 -76.154 -0.004 -1 -11 -11
 
_diffrn_measurement_device              'κ-geometry diffractometer'
_diffrn_measurement_device_type         'Enraf Nonius CAD4'
_diffrn_measurement_method              'non-profiled omega scans'
_diffrn_standards_number                3
_diffrn_standards_interval_time         120
_diffrn_standards_decay_%               0
_diffrn_standards_decay_corr_max        1.018
_diffrn_standards_decay_corr_min        0.965
loop_
    _diffrn_standard_refln_index_h
    _diffrn_standard_refln_index_k
    _diffrn_standard_refln_index_l
1 7 4
3 2 -5
-3 2 -4
 
_diffrn_reflns_number                   9714
_diffrn_reflns_av_R_equivalents         0.0312
_diffrn_reflns_av_unetI/netI            0.0677
_diffrn_reflns_limit_h_min              -1
_diffrn_reflns_limit_h_max              12
_diffrn_reflns_limit_k_min              -18
_diffrn_reflns_limit_k_max              18
_diffrn_reflns_limit_l_min              -18
_diffrn_reflns_limit_l_max              18
_diffrn_reflns_theta_min                2.67
_diffrn_reflns_theta_max                26.01
_diffrn_reflns_theta_full               26.01
_diffrn_measured_fraction_theta_full
                                        0.997
_diffrn_measured_fraction_theta_max
                                        0.997
_reflns_number_total                    8220
_reflns_number_gt                       6128
_reflns_threshold_expression            >2sigma(I)
 
#----------------------------------------------------------------------------#
#                   COMPUTER PROGRAMS USED                                   #
#----------------------------------------------------------------------------#
 
_computing_data_collection              'CAD4 Express (Enraf Nonius, 1994)'
_computing_cell_refinement              'CAD4 Express (Enraf Nonius, 1994)'
_computing_data_reduction               'XCAD4 (Harms & Wocadlo, 1995)'
_computing_structure_solution           'Sir92 (Altomare et al, 1993)'
_computing_structure_refinement         'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics           'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material
                                   'WinGX publication routines (Farrugia, 1999)'
 
#----------------------------------------------------------------------------#
#                   REFINEMENT INFORMATION                                   #
#----------------------------------------------------------------------------#
 
_refine_special_details
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;
_refine_ls_structure_factor_coef        Fsqd
_refine_ls_matrix_type                  full
_refine_ls_weighting_scheme             calc
_refine_ls_weighting_details
         'calc w=1/[σ²(Fo²)+(0.0527P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary            direct
_atom_sites_solution_secondary          difmap
_atom_sites_solution_hydrogens          geom
_refine_ls_hydrogen_treatment           mixed
_refine_ls_extinction_method            none
_refine_ls_number_reflns                8220
_refine_ls_number_parameters            358
_refine_ls_number_restraints            0
_refine_ls_R_factor_all                 0.0681
_refine_ls_R_factor_gt                  0.0385
_refine_ls_wR_factor_ref                0.0929
_refine_ls_wR_factor_gt                 0.0862
_refine_ls_goodness_of_fit_ref          0.949
_refine_ls_restrained_S_all             0.949
_refine_ls_shift/su_max                 0.002
_refine_ls_shift/su_mean                0
_refine_diff_density_max                0.715
_refine_diff_density_min                -1.155
_refine_diff_density_rms                0.111
 
#----------------------------------------------------------------------------#
#                   ATOMIC TYPES, COORDINATES AND THERMAL PARAMETERS         #
#----------------------------------------------------------------------------#
 
loop_
    _atom_type_symbol
    _atom_type_description
    _atom_type_scat_dispersion_real
    _atom_type_scat_dispersion_imag
    _atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 
loop_
    _atom_site_label
    _atom_site_type_symbol
    _atom_site_fract_x
    _atom_site_fract_y
    _atom_site_fract_z
    _atom_site_U_iso_or_equiv
    _atom_site_adp_type
    _atom_site_occupancy
    _atom_site_symmetry_multiplicity
    _atom_site_calc_flag
    _atom_site_refinement_flags
    _atom_site_disorder_assembly
    _atom_site_disorder_group
C1 C 0.8347(6) 0.5858(4) 0.6922(4) 0.0450(13) Uani 1 1 d . . .
H1A H 0.9312 0.5886 0.6976 0.054 Uiso 1 1 calc R . .
H1B H 0.8212 0.5193 0.7028 0.054 Uiso 1 1 calc R . .
C2 C 0.7830(6) 0.6453(4) 0.5945(4) 0.0478(14) Uani 1 1 d . . .
H2A H 0.6873 0.6413 0.5872 0.057 Uiso 1 1 calc R . .
H2B H 0.7955 0.7122 0.5829 0.057 Uiso 1 1 calc R . .
O3 O 0.8592(4) 0.6067(3) 0.5317(3) 0.0569(11) Uani 1 1 d . . .
O4 O 0.4493(4) 0.9223(3) 0.1328(3) 0.0642(12) Uani 1 1 d . . .
C5 C 0.3670(6) 0.9688(4) 0.1882(4) 0.0577(16) Uani 1 1 d . . .
H5A H 0.4182 1.0097 0.2107 0.069 Uiso 1 1 calc R . .
H5B H 0.3335 0.9217 0.2412 0.069 Uiso 1 1 calc R . .
C6 C 0.2514(6) 1.0276(4) 0.1241(4) 0.0495(14) Uani 1 1 d . . .
H6A H 0.2046 0.9854 0.1005 0.059 Uiso 1 1 calc R . .
H6B H 0.2877 1.0735 0.0716 0.059 Uiso 1 1 calc R . .
C10 C 0.8185(6) 0.6418(4) 0.4405(4) 0.0463(13) Uani 1 1 d . . .
C11 C 0.8909(6) 0.5961(4) 0.3826(4) 0.0552(16) Uani 1 1 d . . .
H11 H 0.9597 0.5461 0.4075 0.066 Uiso 1 1 calc R . .
C12 C 0.8598(6) 0.6253(4) 0.2904(4) 0.0545(16) Uani 1 1 d . . .
H12 H 0.9083 0.5954 0.2522 0.065 Uiso 1 1 calc R . .
C13 C 0.7544(6) 0.7009(4) 0.2509(4) 0.0477(14) Uani 1 1 d . . .
C14 C 0.6852(6) 0.7472(4) 0.3080(4) 0.0445(13) Uani 1 1 d . . .
C15 C 0.7182(6) 0.7152(4) 0.4040(4) 0.0483(14) Uani 1 1 d . . .
H15 H 0.6708 0.7447 0.443 0.058 Uiso 1 1 calc R . .
C16 C 0.7177(6) 0.7312(4) 0.1561(4) 0.0591(17) Uani 1 1 d . . .
H16 H 0.7631 0.7004 0.1174 0.071 Uiso 1 1 calc R . .
C17 C 0.6172(6) 0.8048(5) 0.1190(4) 0.0565(16) Uani 1 1 d . . .
H17 H 0.5949 0.8246 0.0557 0.068 Uiso 1 1 calc R . .
C18 C 0.5488(6) 0.8497(4) 0.1777(4) 0.0520(15) Uani 1 1 d . . .
C19 C 0.5814(6) 0.8236(4) 0.2700(4) 0.0515(15) Uani 1 1 d . . .
H19 H 0.5359 0.8557 0.3077 0.062 Uiso 1 1 calc R . .
C111 C 0.5719(3) 0.6241(3) 0.7543(3) 0.0469(14) Uani 1 1 d G . .
C112 C 0.5289(5) 0.5361(2) 0.7605(4) 0.081(2) Uani 1 1 d G . .
H112 H 0.5882 0.4798 0.7829 0.097 Uiso 1 1 calc R . .
C113 C 0.3972(5) 0.5322(4) 0.7330(4) 0.102(3) Uani 1 1 d G . .
H113 H 0.3684 0.4733 0.7371 0.122 Uiso 1 1 calc R . .
C114 C 0.3085(4) 0.6164(5) 0.6994(4) 0.100(3) Uani 1 1 d G . .
H114 H 0.2204 0.6138 0.681 0.121 Uiso 1 1 calc R . .
C115 C 0.3516(4) 0.7045(4) 0.6932(4) 0.094(3) Uani 1 1 d G . .
H115 H 0.2923 0.7608 0.6707 0.112 Uiso 1 1 calc R . .
C116 C 0.4833(4) 0.7083(2) 0.7207(3) 0.069(2) Uani 1 1 d G . .
H116 H 0.5121 0.7672 0.7166 0.083 Uiso 1 1 calc R . .
C121 C 0.7892(4) 0.5316(3) 0.8870(2) 0.0509(14) Uani 1 1 d G . .
C122 C 0.9134(4) 0.4743(3) 0.8998(3) 0.0683(19) Uani 1 1 d G . .
H122 H 0.9755 0.4846 0.8525 0.082 Uiso 1 1 calc R . .
C123 C 0.9449(5) 0.4018(3) 0.9834(3) 0.085(2) Uani 1 1 d G . .
H123 H 1.028 0.3634 0.992 0.102 Uiso 1 1 calc R . .
C124 C 0.8522(6) 0.3865(3) 1.0542(3) 0.097(3) Uani 1 1 d G . .
H124 H 0.8732 0.3379 1.1101 0.116 Uiso 1 1 calc R . .
C125 C 0.7279(6) 0.4438(4) 1.0413(3) 0.123(4) Uani 1 1 d G . .
H125 H 0.6659 0.4336 1.0887 0.147 Uiso 1 1 calc R . .
C126 C 0.6964(4) 0.5164(4) 0.9578(3) 0.094(3) Uani 1 1 d G . .
H126 H 0.6133 0.5547 0.9492 0.113 Uiso 1 1 calc R . .
C211 C 1.0161(4) 0.8737(3) 0.8972(3) 0.0615(18) Uani 1 1 d G . .
C212 C 0.9989(4) 0.8477(4) 0.9926(4) 0.083(3) Uani 1 1 d G . .
H212 H 0.9123 0.85 1.016 0.1 Uiso 1 1 calc R . .
C213 C 1.1114(7) 0.8182(4) 1.0532(3) 0.120(4) Uani 1 1 d G . .
H213 H 1.0999 0.8008 1.1171 0.144 Uiso 1 1 calc R . .
C214 C 1.2409(5) 0.8148(4) 1.0183(5) 0.143(5) Uani 1 1 d G . .
H214 H 1.3161 0.7951 1.0588 0.172 Uiso 1 1 calc R . .
C215 C 1.2581(4) 0.8408(5) 0.9228(5) 0.136(5) Uani 1 1 d G . .
H215 H 1.3447 0.8385 0.8994 0.163 Uiso 1 1 calc R . .
C216 C 1.1456(5) 0.8703(4) 0.8622(4) 0.102(3) Uani 1 1 d G . .
H216 H 1.1571 0.8877 0.7984 0.123 Uiso 1 1 calc R . .
C221 C 0.9151(5) 1.0033(3) 0.7200(3) 0.0563(16) Uani 1 1 d G . .
C222 C 0.9783(5) 1.0765(4) 0.7355(4) 0.086(2) Uani 1 1 d G . .
H222 H 1.0031 1.0731 0.7957 0.104 Uiso 1 1 calc R . .
C223 C 1.0045(6) 1.1547(3) 0.6610(5) 0.118(4) Uani 1 1 d G . .
H223 H 1.0468 1.2037 0.6713 0.142 Uiso 1 1 calc R . .
C224 C 0.9675(7) 1.1598(3) 0.5710(4) 0.117(4) Uani 1 1 d G . .
H224 H 0.985 1.2122 0.5212 0.14 Uiso 1 1 calc R . .
C225 C 0.9043(7) 1.0867(4) 0.5555(3) 0.112(3) Uani 1 1 d G . .
H225 H 0.8795 1.0901 0.4954 0.135 Uiso 1 1 calc R . .
C226 C 0.8781(5) 1.0084(3) 0.6300(3) 0.080(2) Uani 1 1 d G . .
H226 H 0.8358 0.9594 0.6197 0.096 Uiso 1 1 calc R . .
P1 P 0.74778(14) 0.62924(10) 0.78049(10) 0.0393(3) Uani 1 1 d . . .
P2 P 0.87026(15) 0.90730(10) 0.81856(11) 0.0453(4) Uani 1 1 d . . .
Cl1 Cl 0.98591(16) 0.77041(12) 0.69877(13) 0.0664(5) Uani 1 1 d . . .
Cl2 Cl 0.6285(2) 0.77077(14) 0.89199(14) 0.0790(6) Uani 1 1 d . . .
Pt1 Pt 0.80362(2) 0.772824(15) 0.792666(15) 0.03772(8) Uani 1 1 d . . .
 
 
 
#----------------------------------------------------------------------------#
#                   MOLECULAR GEOMETRY                                       #
#----------------------------------------------------------------------------#
 
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
    _geom_bond_atom_site_label_1
    _geom_bond_atom_site_label_2
    _geom_bond_distance
    _geom_bond_site_symmetry_2
    _geom_bond_publ_flag
C1 C2 1.524(7) . ?
C1 P1 1.822(5) . ?
C2 O3 1.422(6) . ?
O3 C10 1.362(6) . ?
O4 C18 1.377(6) . ?
O4 C5 1.433(6) . ?
C5 C6 1.508(7) . ?
C6 P2 1.833(6) 2_676 ?
C10 C15 1.361(7) . ?
C10 C11 1.407(7) . ?
C11 C12 1.352(8) . ?
C12 C13 1.420(8) . ?
C13 C14 1.390(7) . ?
C13 C16 1.400(8) . ?
C14 C15 1.409(7) . ?
C14 C19 1.413(7) . ?
C16 C17 1.366(8) . ?
C17 C18 1.392(8) . ?
C18 C19 1.360(8) . ?
C111 C112 1.39 . ?
C111 C116 1.39 . ?
C111 P1 1.811(3) . ?
C112 C113 1.39 . ?
C113 C114 1.39 . ?
C114 C115 1.39 . ?
C115 C116 1.39 . ?
C121 C122 1.39 . ?
C121 C126 1.39 . ?
C121 P1 1.809(3) . ?
C122 C123 1.39 . ?
C123 C124 1.39 . ?
C124 C125 1.39 . ?
C125 C126 1.39 . ?
C211 C212 1.39 . ?
C211 C216 1.39 . ?
C211 P2 1.804(4) . ?
C212 C213 1.39 . ?
C213 C214 1.39 . ?
C214 C215 1.39 . ?
C215 C216 1.39 . ?
C221 C222 1.39 . ?
C221 C226 1.39 . ?
C221 P2 1.805(4) . ?
C222 C223 1.39 . ?
C223 C224 1.39 . ?
C224 C225 1.39 . ?
C225 C226 1.39 . ?
P1 Pt1 2.3113(14) . ?
P2 C6 1.833(6) 2_676 ?
P2 Pt1 2.3057(15) . ?
Cl1 Pt1 2.2982(15) . ?
Cl2 Pt1 2.2879(16) . ?
 
loop_
    _geom_angle_atom_site_label_1
    _geom_angle_atom_site_label_2
    _geom_angle_atom_site_label_3
    _geom_angle
    _geom_angle_site_symmetry_1
    _geom_angle_site_symmetry_3
    _geom_angle_publ_flag
C2 C1 P1 111.7(3) . . ?
O3 C2 C1 106.8(4) . . ?
C10 O3 C2 116.7(4) . . ?
C18 O4 C5 117.8(4) . . ?
O4 C5 C6 105.1(4) . . ?
C5 C6 P2 112.8(4) . 2_676 ?
C15 C10 O3 125.4(5) . . ?
C15 C10 C11 120.3(5) . . ?
O3 C10 C11 114.3(5) . . ?
C12 C11 C10 119.5(5) . . ?
C11 C12 C13 121.3(5) . . ?
C14 C13 C16 118.4(5) . . ?
C14 C13 C12 118.9(5) . . ?
C16 C13 C12 122.6(5) . . ?
C13 C14 C15 118.9(5) . . ?
C13 C14 C19 120.0(5) . . ?
C15 C14 C19 121.0(5) . . ?
C10 C15 C14 121.0(5) . . ?
C17 C16 C13 121.9(5) . . ?
C16 C17 C18 118.6(6) . . ?
C19 C18 O4 124.6(5) . . ?
C19 C18 C17 121.9(5) . . ?
O4 C18 C17 113.5(5) . . ?
C18 C19 C14 119.2(5) . . ?
C112 C111 C116 120 . . ?
C112 C111 P1 119.5(2) . . ?
C116 C111 P1 120.3(2) . . ?
C113 C112 C111 120 . . ?
C114 C113 C112 120 . . ?
C113 C114 C115 120 . . ?
C116 C115 C114 120 . . ?
C115 C116 C111 120 . . ?
C122 C121 C126 120 . . ?
C122 C121 P1 120.9(3) . . ?
C126 C121 P1 119.0(3) . . ?
C123 C122 C121 120 . . ?
C124 C123 C122 120 . . ?
C123 C124 C125 120 . . ?
C124 C125 C126 120 . . ?
C125 C126 C121 120 . . ?
C212 C211 C216 120 . . ?
C212 C211 P2 120.1(3) . . ?
C216 C211 P2 119.8(3) . . ?
C211 C212 C213 120 . . ?
C214 C213 C212 120 . . ?
C213 C214 C215 120 . . ?
C216 C215 C214 120 . . ?
C215 C216 C211 120 . . ?
C222 C221 C226 120 . . ?
C222 C221 P2 119.0(3) . . ?
C226 C221 P2 120.8(3) . . ?
C221 C222 C223 120 . . ?
C224 C223 C222 120 . . ?
C223 C224 C225 120 . . ?
C224 C225 C226 120 . . ?
C225 C226 C221 120 . . ?
C121 P1 C111 104.8(2) . . ?
C121 P1 C1 103.6(2) . . ?
C111 P1 C1 102.0(2) . . ?
C121 P1 Pt1 111.47(17) . . ?
C111 P1 Pt1 117.21(13) . . ?
C1 P1 Pt1 116.2(2) . . ?
C211 P2 C221 105.6(2) . . ?
C211 P2 C6 103.0(2) . 2_676 ?
C221 P2 C6 101.8(2) . 2_676 ?
C211 P2 Pt1 110.08(17) . . ?
C221 P2 Pt1 118.44(17) . . ?
C6 P2 Pt1 116.4(2) 2_676 . ?
Cl2 Pt1 Cl1 177.29(8) . . ?
Cl2 Pt1 P2 91.27(6) . . ?
Cl1 Pt1 P2 88.70(6) . . ?
Cl2 Pt1 P1 87.75(6) . . ?
Cl1 Pt1 P1 92.02(5) . . ?
P2 Pt1 P1 174.32(5) . . ?
 
